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Diphenyl sulfoxide

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tfus344.KN/ADyer, Harris, et al., 1982Uncertainty assigned by TRC = 3. K; TRC
Tfus343.KN/AVenier, Squires, et al., 1982Uncertainty assigned by TRC = 3. K; TRC
Tfus342.15KN/ASmith and Andrews, 1931Uncertainty assigned by TRC = 1.5 K; by Hg thermometer; TRC
Tfus342.55KN/ASmith and Andrews, 1931Uncertainty assigned by TRC = 0.6 K; by thermocouple; TRC
Quantity Value Units Method Reference Comment
Deltasub23.2 ± 0.7kcal/molVMackle and O'Hare, 1961ALS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dyer, Harris, et al., 1982
Dyer, J.C.; Harris, D.L.; Evans, S.A., Oxygen-17 Nulcear Magnetic RFesonacne SPtroscopy of Sulfoxides and Sulfones. Alkyl Substituent Induced Chemical Shifts, J. Org. Chem., 1982, 47, 3660-4. [all data]

Venier, Squires, et al., 1982
Venier, C.G.; Squires, T.G.; Chen, Y. -Y; Hussmann, G.P.; Shei, J. C>; Smith, G.F., Peroxyfluoroacetic Acid. A Convenient Reagent for the Preparation of Sulfoxides and Sulfones, J. Org. Chem., 1982, 47, 3773-4. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal Energy Studies II. Phenyl Derivatives of Metals, J. Am. Chem. Soc., 1931, 53, 3661-7. [all data]

Mackle and O'Hare, 1961
Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphoxides. Part 1 - The gas-phase heats of formation of diethyl, di-n-propyl, t-butyl ethyl, allyl ethyl and diphenyl sulphoxides, Trans. Faraday Soc., 1961, 57, 2219-2224. [all data]


Notes

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