Stannane, trimethylphenyl-
- Formula: C9H14Sn
- Molecular weight: 240.917
- IUPAC Standard InChIKey: COHOGNZHAUOXPA-UHFFFAOYSA-N
- CAS Registry Number: 934-56-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Phenyltrimethyltin; Phenyltrimethylstannane; Trimethylphenylstannane; Trimethylphenyltin; Trimethylmonophenyltin; Trimethylstannylbenzene; Tin, trimethylphenyl-
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 27.1 ± 1.6 | kcal/mol | Review | Martinho Simões | The enthalpy of formation relies on -44.34 ± 0.88 kcal/mol for the enthalpy of formation of Sn(Me)3(Br)(l). |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | 14.6 ± 1.3 | kcal/mol | Review | Martinho Simões | The enthalpy of formation relies on -44.34 ± 0.88 kcal/mol for the enthalpy of formation of Sn(Me)3(Br)(l). |
Phase change data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔvapH° | 12.5 ± 1.0 | kcal/mol | RSC | Davies, Pope, et al., 1963 |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.83 ± 0.05 | PE | Distefano, Pignataro, et al., 1974 | LLK |
~8.75 | CTS | Pitt, 1973 | LLK |
8.94 | PE | Bischof, Dewar, et al., 1974 | Vertical value; LLK |
Mass spectrum (electron ionization)
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.
Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Chemical Concepts |
NIST MS number | 157512 |
Gas Chromatography
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Packed | Apiezon L | 190. | 1172. | Putnam and Pu, 1965 | Celite; Column length: 1. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Packed | Apiezon L | 1174. | Putnam and Pu, 1965, 2 | Celite, 10. K/min; Column length: 3. m; Tstart: 60. C |
Packed | Apiezon L | 1171. | Putnam and Pu, 1965, 2 | Celite, 15. K/min; Column length: 3. m; Tstart: 60. C |
Packed | Apiezon L | 1169. | Putnam and Pu, 1965, 2 | Celite, 6. K/min; Column length: 3. m; Tstart: 60. C |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A.,
Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin,
Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233
. [all data]
Distefano, Pignataro, et al., 1974
Distefano, G.; Pignataro, S.; Ricci, A.; Colonna, F.P.; Pietropaolo, D.,
Interactions of π-orbitals with the group IV elements studied by ionization energy measurements,
Ann. Chim., 1974, 64, 153. [all data]
Pitt, 1973
Pitt, C.G.,
Hyperconjugation and its role in group IV chemistry,
J. Organomet. Chem., 1973, 61, 49. [all data]
Bischof, Dewar, et al., 1974
Bischof, P.K.; Dewar, M.J.S.; Goodman, D.W.; Jones, T.B.,
Photoelectron spectra of molecules. VI. Hyperconjugation versus pπ-dπ bonding in group IVb compounds,
J. Organomet. Chem., 1974, 82, 89. [all data]
Putnam and Pu, 1965
Putnam, R.C.; Pu, H.,
Retention indices of organotins,
J. Gas Chromatogr., 1965, 3, 5, 160-164, https://doi.org/10.1093/chromsci/3.5.160
. [all data]
Putnam and Pu, 1965, 2
Putnam, R.C.; Pu, H.,
Retention indices of organotins (II),
J. Gas Chromatogr., 1965, 3, 9, 289-293, https://doi.org/10.1093/chromsci/3.9.289
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.