Cyclopropane, hexafluoro-
- Formula: C3F6
- Molecular weight: 150.0225
- IUPAC Standard InChIKey: GQUXQQYWQKRCPL-UHFFFAOYSA-N
- CAS Registry Number: 931-91-9
- Chemical structure:
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Phase change data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 244. | K | N/A | Park, Benning, et al., 1947 | Uncertainty assigned by TRC = 3. K |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.18 ± 0.03 | PI | Berman, Bomse, et al., 1981 | LLK |
11.3 | EI | Lifshitz and Long, 1965 | RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CF+ | 17.3 | ? | EI | Lifshitz and Long, 1965 | RDSH |
CF2+ | 17.4 | ? | EI | Lifshitz and Long, 1965 | RDSH |
CF3+ | 15.38 | ? | EI | Lifshitz and Long, 1965 | RDSH |
C2F3+ | 18.3 | ? | EI | Lifshitz and Long, 1965 | RDSH |
C2F4+ | 11.52 ± 0.03 | CF2 | PI | Berman, Bomse, et al., 1981 | LLK |
C2F4+ | 11.85 | ? | EI | Lifshitz and Long, 1965 | RDSH |
C3F5+ | 14.14 | F | EI | Lifshitz and Long, 1965 | RDSH |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Park, Benning, et al., 1947
Park, J.D.; Benning, A.F.; Downing, F.B.; Laucius, J.F.; McHarness, R.C.,
Synthesis of Tetrafluoroethylene. Pyrolysis of Monochlorodifluoromethane,
Ind. Eng. Chem., 1947, 39, 343-8. [all data]
Berman, Bomse, et al., 1981
Berman, D.W.; Bomse, D.S.; Beauchamp, J.L.,
Photoionization threshold measurements for CF2 loss from perfluoropropylene, Perfluorocyclopropane, and trifluoromethylbenzene. The heat of formation of CF2 and the potential energy surface for C3F6 neutrals and ions,
Int. J. Mass Spectrom. Ion Phys., 1981, 39, 263. [all data]
Lifshitz and Long, 1965
Lifshitz, C.; Long, F.A.,
Appearance potentials and mass spectra of C3F6, C3F5Cl, and c-C3F6,
J. Phys. Chem., 1965, 69, 3741. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy Tboil Boiling point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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