Oxirane, (methoxymethyl)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert L. Brown and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil389.7KN/AWeast and Grasselli, 1989 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C4H8O2+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
9.5PERodin, Chistyakov, et al., 1985LBLHLM
10.08PERodin, Chistyakov, et al., 1985Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHO+14.4 ± 0.2?EIWada and Kiser, 1962RDSH
CH2+21.3 ± 0.5?EIWada and Kiser, 1962RDSH
CH2O+10.9 ± 0.2?EIWada and Kiser, 1962RDSH
CH3+16.0 ± 0.3?EIWada and Kiser, 1962RDSH
CH3O+13.9 ± 0.4?EIWada and Kiser, 1962RDSH
C2HO+13.0 ± 0.3?EIWada and Kiser, 1962RDSH
C2H2+16.2 ± 0.3?EIWada and Kiser, 1962RDSH
C2H2O+12.3 ± 0.3?EIWada and Kiser, 1962RDSH
C2H3+16.3 ± 0.2?EIWada and Kiser, 1962RDSH
C2H3O+13.1 ± 0.2?EIWada and Kiser, 1962RDSH
C2H5O+12.1 ± 0.15?EIWada and Kiser, 1962RDSH
C3H3+15.9 ± 0.4?EIWada and Kiser, 1962RDSH
C3H5O+11.2 ± 0.2CH3OEIWada and Kiser, 1962RDSH
C3H6O+10.2 ± 0.2CH2O?EIWada and Kiser, 1962RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Rodin, Chistyakov, et al., 1985
Rodin, A.A.; Chistyakov, A.B.; Sarkisov, Y.S.; Sergeev, Y.L.; V'yunov, K.A.; Golovin, A.V., Electronic structure and geometric structure of three-member J. Heterocycl. Chem.. I. hotoelectron spectra of gylcidyl and thioglycidyl ethers, Russ. J. Phys. Chem., 1985, 59, 444, In original 764. [all data]

Wada and Kiser, 1962
Wada, Y.; Kiser, R.W., Electron impact spectroscopy of some substituted oxiranes, J. Phys. Chem., 1962, 66, 1652. [all data]


Notes

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