Oxirane, ethenyl-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C4H6O+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
9.52EIHolmes and Lossing, 1986LBLHLM
9.7 ± 0.3EIWada and Kiser, 1962RDSH
9.94PEMcAlduff and Houk, 1977Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHO+12.9 ± 0.6?EIWada and Kiser, 1962RDSH
CH3O+13.3 ± 0.5?EIWada and Kiser, 1962RDSH
C2H2+13.8 ± 0.3?EIWada and Kiser, 1962RDSH
C2H2O+9.8 ± 0.4?EIWada and Kiser, 1962RDSH
C2H3+12.6 ± 0.3CH3CO?EIWada and Kiser, 1962RDSH
C2H3O+10.5 ± 0.2?EIWada and Kiser, 1962RDSH
C3H2+15.8 ± 0.5?EIWada and Kiser, 1962RDSH
C3H3+13.5 ± 0.3?EIWada and Kiser, 1962RDSH
C3H4+11.3 ± 0.3?EIWada and Kiser, 1962RDSH
C3H5+11.1 ± 0.2CO+H?EIWada and Kiser, 1962RDSH

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryMethyl Silicone571.Zenkevich, 1996Program: not specified

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Holmes and Lossing, 1986
Holmes, J.L.; Lossing, F.P., Title unavailable, Personal communication to S.G. Lias, 1986. [all data]

Wada and Kiser, 1962
Wada, Y.; Kiser, R.W., Electron impact spectroscopy of some substituted oxiranes, J. Phys. Chem., 1962, 66, 1652. [all data]

McAlduff and Houk, 1977
McAlduff, E.J.; Houk, K.N., Photoelectron spectra of substituted oxiranes and thiiranes. Substituent effects on ionization potentials involving σ orbitals, Can. J. Chem., 1977, 55, 318. [all data]

Zenkevich, 1996
Zenkevich, I.G., Informational Maitenance of Gas Chromatographic Identification of Organic Compounds in Ecoanalytical Investigations, Z. Anal. Chem., 1996, 51, 11, 1140-1148. [all data]


Notes

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