2-Propanamine, N,N,2-trimethyl-
- Formula: C6H15N
- Molecular weight: 101.1900
- IUPAC Standard InChIKey: OXQMIXBVXHWDPX-UHFFFAOYSA-N
- CAS Registry Number: 918-02-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: t-C4H9N(CH3)2; N,N-Dimethyl-t-butylamine
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Phase change data
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 363.65 | K | N/A | Calderbank and Ghosh, 1960 | Uncertainty assigned by TRC = 2. K; TRC |
Tboil | 362.8 | K | N/A | Grovenstein, Blanchard, et al., 1959 | Uncertainty assigned by TRC = 1.5 K; TRC |
Tboil | 362.15 | K | N/A | Meiners, Bolze, et al., 1958 | Uncertainty assigned by TRC = 2. K; TRC |
Tboil | 363.8 | K | N/A | Spialter and Pappalardo, 1957 | Uncertainty assigned by TRC = 1. K; TRC |
Tboil | 362.65 | K | N/A | Bortnick, Luskin, et al., 1956 | Uncertainty assigned by TRC = 2. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 183.15 | K | N/A | Spialter and Pappalardo, 1957 | Uncertainty assigned by TRC = 5. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 34.8 | kJ/mol | A | Stephenson and Malanowski, 1987 | Based on data from 283. to 318. K.; AC |
Gas phase ion energetics data
Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Proton affinity (review) | 979.6 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 948.6 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.08 | PE | Nelsen, 1984 | Vertical value; LBLHLM |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C2H6N+ | 10.96 ± 0.07 | tert-C4H9 | EI | Solka and Russell, 1974 | LLK |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | NIST Mass Spectrometry Data Center, 1992 |
NIST MS number | 125409 |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Calderbank and Ghosh, 1960
Calderbank; Ghosh,
The preparation and isomerization of some basic esters of 00(prime)- diethyl hydrogen phosphorothioate,
J. Chem. Soc., 1960, 1960, 637. [all data]
Grovenstein, Blanchard, et al., 1959
Grovenstein, E.; Blanchard; Gordon; Stevenson,
J. Am. Chem. Soc., 1959, 81, 4842. [all data]
Meiners, Bolze, et al., 1958
Meiners; Bolze; Scherer; Morriss,
J. Org. Chem., 1958, 23, 1122. [all data]
Spialter and Pappalardo, 1957
Spialter, L.; Pappalardo, J.A.,
Characterization of Aliphatic Tertiary Amines.,
J. Org. Chem., 1957, 22, 840. [all data]
Bortnick, Luskin, et al., 1956
Bortnick, N.; Luskin, L.S.; Hurwitz, M.D.; Craig, W.E.; Exner, L.J.; Mirza, J.,
T-carbinamines, rr'r''cnh(2): I reaction with alkyl halides and alkylene oxides,
J. Am. Chem. Soc., 1956, 78, 4039. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Nelsen, 1984
Nelsen, S.F.,
Ionization from nitrogen and oxygen lone pairs: A comparison of trialkylamine, dialkyl ether, tetraalkylhydrazine, and dialkyl peroxide photoelectron spectroscopic ionization potentials,
J. Org. Chem., 1984, 49, 1891. [all data]
Solka and Russell, 1974
Solka, B.H.; Russell, M.E.,
Energetics of formation of some structural isomers of gaseous C2H5O+ C2H6N+ ions,
J. Phys. Chem., 1974, 78, 1268. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References
- Symbols used in this document:
AE Appearance energy Tboil Boiling point Tfus Fusion (melting) point ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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