Samarium, bis(η5-pentamethylcyclopentadienyl)-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

Tetrahydrofuran (solution) + C20H30Sm (solution) = C24H38OSm (solution)

By formula: C4H8O (solution) + C20H30Sm (solution) = C24H38OSm (solution)

Quantity Value Units Method Reference Comment
Δr-7.29 ± 0.41kcal/molRSCNolan, Stern, et al., 1989solvent: Toluene

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
5.37PEGreen, Hohl, et al., 1987Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nolan, Stern, et al., 1989
Nolan, S.P.; Stern, D.; Marks, T.J., J. Am. Chem. Soc., 1989, 111, 7844. [all data]

Green, Hohl, et al., 1987
Green, J.C.; Hohl, D.; Rosch, N., (Cyclopentadienyl)lanthanide compounds Ln(C5Me5)2 (Ln = Sm, Eu, Yb): Photoelectron spectra and molecular orbital calculations, Organometallics, 1987, 6, 712. [all data]


Notes

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