Benzene, 1,1'-(diazomethylene)bis-

• Formula: C₁₃H₁₀N₂
• Molecular weight: 194.2319
• IUPAC Standard InChI: InChI=1S/C13H10N2/c14-15-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H Copy

  
• IUPAC Standard InChIKey: ITLHXEGAYQFOHJ-UHFFFAOYSA-N Copy
• CAS Registry Number: 883-40-9
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Methane, diazodiphenyl-; Diazodiphenylmethane; Diphenyldiazomethane; 1,1-Diphenyldiazomethane
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• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

=  + 

By formula: C₁₃H₁₀N₂ = C₁₃H₁₀ + N₂

 +  =  + 

By formula: O₂ + C₁₃H₁₀N₂ = N₂ + C₁₃H₁₀O₂

 +  = C₁₃H₂₈O₄ + 

By formula: C₂H₆O + C₁₃H₁₀N₂ = C₁₃H₂₈O₄ + N₂

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Simon and Peters, 1983
Simon, J.D.; Peters, K.S., Determination of the heat of reaction for the formation of diphenylcarbene from diphenyldiazomethane using photoacoustic calorimetry, J. Am. Chem. Soc., 1983, 105, 5156-5158. [all data]

Hartstock, Kanabus-Kaminska, et al., 1989
Hartstock, F.W.; Kanabus-Kaminska, J.M.; Griller, D., Heat of formation of benzophenone oxide [1], Int. J. Chem. Kinet., 1989, 21, 157-163. [all data]

Okubo, Ito, et al., 1985
Okubo, J.; Ito, H.; Hishi, T.; Kobayashi, T., Intramolecular orbital interactions in and conformation of N,N'-diphenylcarbodiimide studied by photoelectron spectroscopy, Tetrahedron Lett., 1985, 26, 643. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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