Decamethyl-[5]pericyclyne

• Formula: C₂₅H₃₀
• Molecular weight: 330.5057
• IUPAC Standard InChI: InChI=1S/C25H30/c1-21(2)11-13-22(3,4)15-17-24(7,8)19-20-25(9,10)18-16-23(5,6)14-12-21/h1-10H3 Copy

  
• IUPAC Standard InChIKey: QOIXDYKIHPKUIQ-UHFFFAOYSA-N Copy
• CAS Registry Number: 88057-40-3
• Chemical structure:
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• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

10 +  = C₂₅H₅₀

By formula: 10H₂ + C₂₅H₃₀ = C₂₅H₅₀

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Scott, Cooney, et al., 1988
Scott, L.T.; Cooney, M.J.; Rogers, D.W.; Dejroongruang, K., Homoaromaticity in a cyclic polyacetylene, J. Am. Chem. Soc., 1988, 110, 7244-7245. [all data]

Houk, Scott, et al., 1985
Houk, K.N.; Scott, L.T.; Rondan, N.G.; Spellmeyer, D.C.; Reinhardt, G.; Hyun, J.L.; DeCicco, G.J.; Weiss, R.; Chen, M.H.M.; Bass, L.S.; Clardy, J.; Jorgensen, F.S.; Eaton, T.A.; Sarkozi, V.; Petit, C.M., Pericyclynes: 'Exploded cycloalkanes' with unusual orbital interactions and conformational properties. MM2 and STO-3G calculations, x-ray crystal structures, photoelectron spectra, and electron transmission spectra, J. Am. Chem. Soc., 1985, 107, 6556. [all data]

Notes

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• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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