BaOCH3

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 12923 ± 5 gas Wormsbecher and Suenram, 1982
Brazier, Ellingboe, et al., 1986

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 11448 ± 5 gas Wormsbecher and Suenram, 1982
Brazier, Ellingboe, et al., 1986
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 4 BaO stretch 342 ± 5 gas LF Brazier, Ellingboe, et al., 1986

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 4 BaO stretch 375 ± 5 gas LF Brazier, Ellingboe, et al., 1986
e 8 BaOC bend 127 gas LF Brazier, Ellingboe, et al., 1986

Additional references: Jacox, 1994, page 315

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wormsbecher and Suenram, 1982
Wormsbecher, R.F.; Suenram, R.D., Laser spectroscopy and chemiluminescence from the monomethoxides of Ca, Sr, and Ba, J. Mol. Spectrosc., 1982, 95, 2, 391, https://doi.org/10.1016/0022-2852(82)90138-2 . [all data]

Brazier, Ellingboe, et al., 1986
Brazier, C.R.; Ellingboe, L.C.; Kinsey-Nielsen, S.; Bernath, P.F., Laser spectroscopy of alkaline earth monoalkoxide free radicals, J. Am. Chem. Soc., 1986, 108, 9, 2126, https://doi.org/10.1021/ja00269a002 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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