Dimethyl phosphite

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap11.2kcal/molGSButrow, Buchanan, et al., 2009Based on data from 243. to 443. K.

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
11.2368.N/AFan and Wang, 2010Based on data from 353. to 443. K.
11.5243.GSButrow, Buchanan, et al., 2009Based on data from 243. to 443. K.
11.4263.GSButrow, Buchanan, et al., 2009Based on data from 243. to 443. K.
11.1313.GSButrow, Buchanan, et al., 2009Based on data from 243. to 443. K.
11.0333.GSButrow, Buchanan, et al., 2009Based on data from 243. to 443. K.
10.9373.GSButrow, Buchanan, et al., 2009Based on data from 243. to 443. K.
9.25361.AStephenson and Malanowski, 1987Based on data from 346. to 456. K. See also Dykyj, 1970.

Gas phase ion energetics data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C2H7O3P+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)213.9kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity206.1kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
10.53PEZverev and Villem, 1980LLK
10.53PEZverev, Villem, et al., 1979LLK
10.5EIFischler and Halmann, 1964RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH4O3P+11.9?EIFischler and Halmann, 1964RDSH
C2H6O3P+12.7HEIFischler and Halmann, 1964RDSH
PHO3+11.2?EIFischler and Halmann, 1964RDSH
PO+16.3?EIFischler and Halmann, 1964RDSH
PO3+13.5?EIFischler and Halmann, 1964RDSH

De-protonation reactions

C2H6O3P- + Hydrogen cation = Dimethyl phosphite

By formula: C2H6O3P- + H+ = C2H7O3P

Quantity Value Units Method Reference Comment
Δr356.5 ± 3.6kcal/molG+TSMcDonald, Chowdhury, et al., 1987gas phase; Acidity between MeNO2, EtSH. Acid taken as (MeO)2P(O)H.; B
Quantity Value Units Method Reference Comment
Δr349.3 ± 3.5kcal/molIMRBMcDonald, Chowdhury, et al., 1987gas phase; Acidity between MeNO2, EtSH. Acid taken as (MeO)2P(O)H.; B
Δr351.0 ± 4.0kcal/molIMRBAnderson, DePuy, et al., 1984gas phase; Between MeSH, H2S; B

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW- 989
NIST MS number 230474

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References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Butrow, Buchanan, et al., 2009
Butrow, Ann B.; Buchanan, James H.; Tevault, David E., Vapor Pressure of Organophosphorus Nerve Agent Simulant Compounds, J. Chem. Eng. Data, 2009, 54, 6, 1876-1883, https://doi.org/10.1021/je8010024 . [all data]

Fan and Wang, 2010
Fan, Chuan-Lei; Wang, Li-Sheng, Vapor Pressure of Dimethyl Phosphite and Dimethyl Methylphosphonate, J. Chem. Eng. Data, 2010, 55, 1, 479-481, https://doi.org/10.1021/je900258f . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1970
Dykyj, J., Petrochemica, 1970, 10, 2, 51. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Zverev and Villem, 1980
Zverev, V.V.; Villem, Y.Y., Ionizationp potentials of phosphoryl compounds, J. Struct. Chem., 1980, 21, 22, In original 30. [all data]

Zverev, Villem, et al., 1979
Zverev, V.V.; Villem, Ya.Ya.; Bel'skii, V.E.; Kitaev, Yu.P., The photoelectronic spectra of phosphoryl compounds, Izv. Akad. Nauk SSSR, Ser. Khim., 1979, 1, 84. [all data]

Fischler and Halmann, 1964
Fischler, J.; Halmann, M., Electron-impact studies of phosphorus compounds, J. Chem. Soc., 1964, 31. [all data]

McDonald, Chowdhury, et al., 1987
McDonald, R.M.; Chowdhury, A.K.; Gung, W.Y.; DeWitt, K.D., Nucleophilic Reactivity in Anionic Ion-Molecule Reactions in Nucleophilicity, Harris, J.M, McManus, S.P. Eds., Amer. Chem. Soc, 1987. [all data]

Anderson, DePuy, et al., 1984
Anderson, D.R.; DePuy, C.H.; Filley, J.; Bierbaum, V.M., Gas Phase Chemistry of Trimethyl Phosphite, J. Am. Chem. Soc., 1984, 106, 22, 6513, https://doi.org/10.1021/ja00334a009 . [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References