Methane, nitroso-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

2Methane, nitroso- = C2H6N2O2

By formula: 2CH3NO = C2H6N2O2

Quantity Value Units Method Reference Comment
Δr-16.0kcal/molEqkChristie, Frost, et al., 1965gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to CH3NO+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
9.3PEFrost, Lau, et al., 1982LBLHLM
9.3PEChong, Frost, et al., 1982LBLHLM
10.8 ± 0.3EIThomassy and Lampe, 1970RDSH
9.68 ± 0.05PEFrost, Lau, et al., 1982Vertical value; LBLHLM
9.68 ± 0.05PEChong, Frost, et al., 1982Vertical value; LBLHLM
9.76 ± 0.05PEErnsting, Pfab, et al., 1980Vertical value; LLK
9.8PERao, 1975Vertical value; LLK
8.7 ± 0.1PEEgdell, Green, et al., 1975Vertical value; LLK
9.8PEBergmann and Bock, 1975Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Christie, Frost, et al., 1965
Christie, M.I.; Frost, J.S.; Voisey, M.A., Kinetics of some reactions of nitrosoalkanes, Trans. Faraday Soc., 1965, 61, 674-680. [all data]

Frost, Lau, et al., 1982
Frost, D.C.; Lau, W.M.; McDowell, C.A.; Westwood, N.P.C., A study by He I photoelectron spectroscopy of monomeric nitrosomethane, the cis and trans dimers, and formaldoxime, J. Phys. Chem., 1982, 86, 3577. [all data]

Chong, Frost, et al., 1982
Chong, D.P.; Frost, D.C.; Lau, W.M.; McDowell, C.A., Shake-up satellites in HeI photoelectron spectra: N2O4 and CH3NO, Chem. Phys. Lett., 1982, 90, 332. [all data]

Thomassy and Lampe, 1970
Thomassy, F.A.; Lampe, F.W., A mass spectrometric study of the dimerization of nitrosomethane, J. Phys. Chem., 1970, 74, 1188. [all data]

Ernsting, Pfab, et al., 1980
Ernsting, N.P.; Pfab, J.; Green, J.C.; Romelt, J., Photoelectron spectra of nitrosomethane, t-nitrosobutane and some perhalogenonitrosomethanes, J. Chem. Soc. Faraday Trans. 2, 1980, 76, 844. [all data]

Rao, 1975
Rao, C.N.R., Lone-pair ionization bands of chromophores in the photoelectron spectra of organic molecules, Indian J. Chem., 1975, 13, 950. [all data]

Egdell, Green, et al., 1975
Egdell, R.; Green, J.C.; Rao, C.N.R.; Gowenlock, B.G.; Pfab, J., He(I) photoelectron studies of C-nitroso compounds, J. Chem. Soc. Faraday Trans. 2, 1975, 988. [all data]

Bergmann and Bock, 1975
Bergmann, H.; Bock, H., Photoelectron spectra molecular properties, XLVI nitroso compounds - electron-rich molecules, Z. Naturforsch. B:, 1975, 30, 629. [all data]


Notes

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