Ni(CO) anion

Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
ΔfH°gas16.6 ± 5.8kcal/molR-EAStevens, Feigerle, et al., 1982 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CNiO- • 4294967295Carbon monoxide) + Carbon monoxide = CNiO-

By formula: (CNiO- • 4294967295CO) + CO = CNiO-

Quantity Value Units Method Reference Comment
ΔrH°33.0 ± 5.8kcal/molN/AStevens, Feigerle, et al., 1982gas phase
ΔrH°32.4 ± 5.8kcal/molCIDTSunderlin, Wang, et al., 1992gas phase; Affinity: CO..Ni-

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td = 6490 ± 100 gas Stevens, Feigerle, et al., 1982

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 1 CO stretch 1860.6 Ne IR Liang, Zhou, et al., 2000
1 CO stretch 1850.1 Ar IR Zhou and Andrews, 1998
1 CO stretch 1847.0 Ar IR Zhou and Andrews, 1998

Additional references: Jacox, 1998, page 171; Jacox, 2003, page 86

Notes

dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stevens, Feigerle, et al., 1982
Stevens, A.E.; Feigerle, C.S.; Lineberger, W.C., Laser Photoelectron Spectrometry of Ni(CO)n-, n=1-3, J. Am. Chem. Soc., 1982, 104, 19, 5026, https://doi.org/10.1021/ja00383a004 . [all data]

Sunderlin, Wang, et al., 1992
Sunderlin, L.S.; Wang, D.; Squires, R.R., Metal Carbonyl Bond Strengths in Fe(CO)n- and Ni(CO)n-, J. Am. Chem. Soc., 1992, 114, 8, 2788, https://doi.org/10.1021/ja00034a004 . [all data]

Liang, Zhou, et al., 2000
Liang, B.; Zhou, M.; Andrews, L., Reactions of Laser-Ablated Ni, Pd, and Pt Atoms with Carbon Monoxide: Matrix Infrared Spectra and Density Functional Calculations on M(CO), J. Phys. Chem. A, 2000, 104, 17, 3905, https://doi.org/10.1021/jp993646q . [all data]

Zhou and Andrews, 1998
Zhou, M.; Andrews, L., Matrix Infrared Spectra and Density Functional Calculations of Ni(CO), J. Am. Chem. Soc., 1998, 120, 44, 11499, https://doi.org/10.1021/ja9820644 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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