Chloro(dimethyl)phosphine

• Formula: C₂H₆ClP
• Molecular weight: 96.496
• IUPAC Standard InChI: InChI=1S/C2H6ClP/c1-4(2)3/h1-2H3 Copy

  
• IUPAC Standard InChIKey: ZLVVDNKTHWEIOG-UHFFFAOYSA-N Copy
• CAS Registry Number: 811-62-1
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: (CH3)2PCl; Dimethyl chloro phosphine; Phosphinous chloride, dimethyl-
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• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Enthalpy of sublimation

Gas phase ion energetics data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Burg and Slota, 1958
Burg, A.B.; Slota, P.J., Dimethylaminodimethylphosphine, J. Am. Chem. Soc., 1958, 80, 1107. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Burg and Slota, 1958, 2
Burg, Anton B.; Slota, Peter J., Dimethylaminodimethylphosphine ¹, J. Am. Chem. Soc., 1958, 80, 5, 1107-1109, https://doi.org/10.1021/ja01538a023 . [all data]

Bock and Bankmann, 1986
Bock, H.; Bankmann, M., H₃C-P=CH₂: An ylide with two-Coordinate phosphorus?, Angew. Chem. Int. Ed. Engl., 1986, 25, 265. [all data]

Lappert, Pedley, et al., 1975
Lappert, M.F.; Pedley, J.B.; Wilkins, B.T.; Stelzer, O.; Unger, E., Bonding studies of compounds of boron and the group 3-5 elements. Part XIII. He(I) photoelectron spectra of phosphines R_nPX_3-n (R=Me or Bu'; X=H, Cl, or F; n=1-3), (Me₂N)_nPCl_3-n(n=1-3), and (R₂N)PF₂(R=Me or Et), J. Chem. Soc. Dalton Trans., 1975, 1207. [all data]

Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  Tfus	Fusion (melting) point
  ΔsubH	Enthalpy of sublimation
  ΔvapH	Enthalpy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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