Chloro(dimethyl)phosphine

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Phase change data

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tfus272.KN/ABurg and Slota, 1958Uncertainty assigned by TRC = 0.2 K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
32.9288.AStephenson and Malanowski, 1987Based on data from 273. to 306. K. See also Burg and Slota, 1958, 2.; AC

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Reference Comment
55.5253.Stephenson and Malanowski, 1987Based on data from 233. to 268. K. See also Burg and Slota, 1958, 2.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
9.0PEBock and Bankmann, 1986LBLHLM
8.7PELappert, Pedley, et al., 1975LLK
9.3PEBock and Bankmann, 1986Vertical value; LBLHLM
9.20PELappert, Pedley, et al., 1975Vertical value; LLK

Mass spectrum (electron ionization)

Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1994
NIST MS number 133324

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References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Burg and Slota, 1958
Burg, A.B.; Slota, P.J., Dimethylaminodimethylphosphine, J. Am. Chem. Soc., 1958, 80, 1107. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Burg and Slota, 1958, 2
Burg, Anton B.; Slota, Peter J., Dimethylaminodimethylphosphine 1, J. Am. Chem. Soc., 1958, 80, 5, 1107-1109, https://doi.org/10.1021/ja01538a023 . [all data]

Bock and Bankmann, 1986
Bock, H.; Bankmann, M., H3C-P=CH2: An ylide with two-Coordinate phosphorus?, Angew. Chem. Int. Ed. Engl., 1986, 25, 265. [all data]

Lappert, Pedley, et al., 1975
Lappert, M.F.; Pedley, J.B.; Wilkins, B.T.; Stelzer, O.; Unger, E., Bonding studies of compounds of boron and the group 3-5 elements. Part XIII. He(I) photoelectron spectra of phosphines RnPX3-n (R=Me or Bu'; X=H, Cl, or F; n=1-3), (Me2N)nPCl3-n(n=1-3), and (R2N)PF2(R=Me or Et), J. Chem. Soc. Dalton Trans., 1975, 1207. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References