SiFCl3+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 39530 ± 320 gas Grabandt, de Lange, et al., 1991

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 22750 ± 320 gas Grabandt, de Lange, et al., 1991
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 3 SiCl3 umbrella 250 ± 50 gas PE Grabandt, de Lange, et al., 1991

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 15890 ± 320 gas Grabandt, de Lange, et al., 1991

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 13150 ± 320 gas Grabandt, de Lange, et al., 1991

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 6940 ± 320 gas Grabandt, de Lange, et al., 1991

Additional references: Jacox, 1994, page 296

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Grabandt, de Lange, et al., 1991
Grabandt, O.; de Lange, C.A.; Mooyman, R.; Vernooijs, P., He(I) photoelectron spectroscopy of SiF2Cl2 and SiFCl3, Chem. Phys. Lett., 1991, 184, 1-3, 221, https://doi.org/10.1016/0009-2614(91)87191-D . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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