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HSiF3+


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   F


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 52120 ± 320 gas Cradock, Ebsworth, et al., 1973


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 SiF3 stretch 725 ± 40 gas PE Cradock, Ebsworth, et al., 1973
3 Deformation 330 ± 40 gas PE Cradock, Ebsworth, et al., 1973

State:   E


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 33320 ± 320 gas Cradock, Ebsworth, et al., 1973

State:   D


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 30010 ± 320 gas Cradock, Ebsworth, et al., 1973


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 SiF3 stretch 790 ± 40 gas PE Cradock, Ebsworth, et al., 1973

State:   C


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 22270 ± 320 gas Cradock, Ebsworth, et al., 1973

State:   B


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 15330 ± 320 gas Cradock, Ebsworth, et al., 1973

State:   A


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Txx = 11780 ± 320 gas Cradock, Ebsworth, et al., 1973

Additional references: Jacox, 1994, page 276

Notes

xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cradock, Ebsworth, et al., 1973
Cradock, S.; Ebsworth, E.A.V.; Robertson, A., Photoelectron spectra of some silyl and germyl transition-metal carbonyls and related specis, J. Chem. Soc. Dalton Trans., 1973, 22. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]


Notes

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