Hydroxymethyl-c-d2 radical

Formula: CHD₂O
Molecular weight: 33.0462
CAS Registry Number: 79825-55-1
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Data at other public NIST sites:
- Gas Phase Kinetics Database
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Gas phase ion energetics data

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

View reactions leading to CHD₂O⁺ (ion structure unspecified)

Ionization energy determinations

IE (eV)	Method	Reference	Comment
7.54 ± 0.02	PI	Kuo, Zhang, et al., 1994	LL
7.540 ± 0.006	PI	Ruscic and Berkowitz, 1991	LL
7.55 ± 0.01	PE	Dyke, 1987	LBLHLM

References

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Kuo, Zhang, et al., 1994
Kuo, S.-C.; Zhang, Z.; Klemm, R.B.; Liebman, J.F.; Stief, L.J.; Nesbitt, F.L., Photoionization of hydroxymethyl (CD₂OH and CD₃O) radicals: Photoion efficiency spectra, ionization energies and thermochemistry, J. Phys. Chem., 1994, 98, 4026. [all data]

Ruscic and Berkowitz, 1991
Ruscic, B.; Berkowitz, J., Photoionization mass spectrometric studies of the isomeric transient species CD₂OH and CD₃O, J. Chem. Phys., 1991, 95, 4033. [all data]

Dyke, 1987
Dyke, J.M., Properties of gas-phase ions, J. Chem. Soc. Faraday Trans., 1987, 83, 69. [all data]

Notes

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Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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