rubidium chloride
- Formula: ClRb
- Molecular weight: 120.921
- IUPAC Standard InChI: InChI=1S/ClH.Rb/h1H;/q;+1/p-1
- IUPAC Standard InChIKey: FGDZQCVHDSGLHJ-UHFFFAOYSA-M
- CAS Registry Number: 7791-11-9
- Chemical structure:
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Phase change data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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| Temperature (K) | A | B | C | Reference | Comment |
|---|---|---|---|---|---|
| 1065. to 1654. | 4.49466 | 6763.035 | -147.495 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| IE (evaluated) | 8.50 ± 0.03 | eV | N/A | N/A | L |
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 0.543 ± 0.010 | LPES | Miller, Leopold, et al., 1986 | B |
| >1.53999 | EIAE | Ebinghaus, 1964 | From (RbCl)2; B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.2 | EI | Williams, 1982 | LBLHLM |
| 8.3 ± 0.1 | PE | Potts and Price, 1977 | LLK |
| 8.3 ± 0.1 | PE | Potts, Williams, et al., 1974 | LLK |
| 8.50 ± 0.03 | PI | Berkowitz, 1971 | LLK |
| 8.7 | PE | Goodman, Allen, et al., 1974 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| Rb+ | 8.70 ± 0.03 | Cl | PI | Berkowitz, 1971 | LLK |
| Rb+ | 9.2 ± 0.5 | Cl | EI | Hastie and Swingler, 1969 | RDSH |
| Rb+ | 8.9 ± 0.5 | Cl | EI | Bloom, Hastie, et al., 1968 | RDSH |
| Rb+ | 21.17 ± 0.04 | Cl(-) | PE | Potts and Price, 1977 | Vertical value; LLK |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C.,
Electron Affinities of the Alkali Halides and the Structure of their Negative Ions,
J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091
. [all data]
Ebinghaus, 1964
Ebinghaus, H.Z.,
Negative Ionen aus Alkalihalogeniden und Electronenaffinitaten der Alkalimetalle und Alkalihalogenide,
Z. Naturfor., 1964, 19A, 727. [all data]
Williams, 1982
Williams, D.J.,
Mass spectrometric study of the vaporization of the alkali chloride-cuprous chloride systems,
Aust. J. Chem., 1982, 35, 1531. [all data]
Potts and Price, 1977
Potts, A.W.; Price, W.C.,
Photoelectron studies of ionic materials using molecular beam techniques,
Phys. Scr., 1977, 16, 191. [all data]
Potts, Williams, et al., 1974
Potts, A.W.; Williams, T.A.; Price, W.C.,
Photoelectron spectra and electronic structure of diatomic alkali halides,
Proc. Roy. Soc. London A, 1974, 341, 147. [all data]
Berkowitz, 1971
Berkowitz, J.,
Photoionization mass spectrometry photoelectron spectroscopy of high temperature vapor,
Adv. High Temp. Chem., 1971, 3, 123. [all data]
Goodman, Allen, et al., 1974
Goodman, T.D.; Allen, J.D., Jr.; Cusachs, L.C.; Schweitzer, G.K.,
The photoelectron spectra of gaseous alkali halides,
J. Electron Spectrosc. Relat. Phenom., 1974, 3, 289. [all data]
Hastie and Swingler, 1969
Hastie, J.W.; Swingler, D.L.,
Use of the quadrupole mass filter for high-temperature studies,
High Temp. Sci., 1969, 1, 46. [all data]
Bloom, Hastie, et al., 1968
Bloom, H.; Hastie, J.W.; Morrison, J.D.,
Ionization and dissociation of the alkali halides by electron impact,
J. Phys. Chem., 1968, 72, 3041. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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