cerium triiodide


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

Iodide + CeI3 = (Iodide • CeI3)

By formula: I- + CeI3 = (I- • CeI3)

Quantity Value Units Method Reference Comment
Δr280. ± 33.kJ/molTDEqChantry, 1976gas phase; B,M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KMSChantry, 1976gas phase; heated collision chamber; M
Quantity Value Units Method Reference Comment
Δr250. ± 42.kJ/molTDEqChantry, 1976gas phase; B

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
>0.29999IMRBChantry, 1976CeI2- + CeI3 ->.; B

Ionization energy determinations

IE (eV) Method Reference Comment
8.7PERuscic, Goodman, et al., 1983LBLHLM
9.1 ± 0.1EIChantry, 1976, 2LLK
9.6 ± 0.5EIHirayama and Castle, 1973LLK
9.71PERuscic, Goodman, et al., 1983Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Ce+16.75 ± 0.15?EIChantry, 1976, 2LLK
Ce+17.7 ± 0.53IEIHirayama and Castle, 1973LLK
ICe+13.15 ± 0.15I2?EIChantry, 1976, 2LLK
ICe+13.6 ± 0.52IEIHirayama and Castle, 1973LLK
I2Ce+9.6 ± 0.1IEIChantry, 1976, 2LLK
I2Ce+9.7 ± 0.5IEIHirayama and Castle, 1973LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chantry, 1976
Chantry, P.J., Negative Ion Formation in Cerium Triiodide, J. Chem. Phys., 1976, 65, 11, 4412, https://doi.org/10.1063/1.432992 . [all data]

Ruscic, Goodman, et al., 1983
Ruscic, B.; Goodman, G.L.; Berkowitz, J., Photoelectron spectra of the lanthanide trihalides and their interpretation, J. Chem. Phys., 1983, 78, 5443. [all data]

Chantry, 1976, 2
Chantry, P.J., Positive ion appearance potentials measured in CeI3, J. Chem. Phys., 1976, 65, 4421. [all data]

Hirayama and Castle, 1973
Hirayama, C.; Castle, P.M., Mass spectra of rare earth triiodides, J. Phys. Chem., 1973, 77, 3110. [all data]


Notes

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