Phosphorus tribromide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
1.59 ± 0.15NBIEMathur, Rothe, et al., 1976B

Ionization energy determinations

IE (eV) Method Reference Comment
10.1 ± 0.1EIVarmuza and Krenmayr, 1971LLK
9.85EIMuller and Fenderl, 1969RDSH
10.0 ± 0.2EIKiser, Dillard, et al., 1969RDSH
9.99PEDaamen, Boxhoorn, et al., 1978Vertical value; LLK
10.00PENicholson and Rademacher, 1974Vertical value; LLK
9.96PEBerkosky, Ellison, et al., 1973Vertical value; LLK
10.00 ± 0.03PECox, Evans, et al., 1972Vertical value; LLK
10.0PEBetteridge, Thompson, et al., 1972Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Br+17.1 ± 0.5?EIKiser, Dillard, et al., 1969RDSH
PBr+14.2 ± 0.2?EIVarmuza and Krenmayr, 1971LLK
PBr+15.6 ± 0.3?EIKiser, Dillard, et al., 1969RDSH
PBr2+11.2 ± 0.1BrEIVarmuza and Krenmayr, 1971LLK
PBr2+11.4 ± 0.2BrEIKiser, Dillard, et al., 1969RDSH
P+16.7 ± 0.7Br2+BrEIVarmuza and Krenmayr, 1971LLK
P+20.1 ± 0.5?EIKiser, Dillard, et al., 1969RDSH


Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mathur, Rothe, et al., 1976
Mathur, B.P.; Rothe, E.W.; Tang, S.Y.; Reck, G., Negative ions from phosphorus halides due to cesium charge exchange, J. Chem. Phys., 1976, 64, 565. [all data]

Varmuza and Krenmayr, 1971
Varmuza, K.; Krenmayr, P., Massenspektrometrische untersuchungen einfacher und gemischter phosphortrihalogenide, Monatsh. Chem., 1971, 102, 1037. [all data]

Muller and Fenderl, 1969
Muller, J.; Fenderl, K., Massenspektren und Ionisierungspotentiale von C5H5Mn(CO)2PX3-Komplexen, J. Organometal. Chem., 1969, 19, 123. [all data]

Kiser, Dillard, et al., 1969
Kiser, R.W.; Dillard, J.G.; Dugger, D.L., Mass spectrometry of inorganic halides, Advan. Chem. Ser., 1969, 72, 153. [all data]

Daamen, Boxhoorn, et al., 1978
Daamen, H.; Boxhoorn, G.; Oskam, A., U. V. photoelectron (He I and He II) studies of M(CO)5PX3 (M=Cr, Mo, W and X=F, Cl, Br), Inorg. Chim. Acta, 1978, 28, 263. [all data]

Nicholson and Rademacher, 1974
Nicholson, D.G.; Rademacher, P., Photoelectron spectra and electronic structures of antimony(III) halides, Acta Chem. Scand. Ser. A:, 1974, 28, 1136. [all data]

Berkosky, Ellison, et al., 1973
Berkosky, J.L.; Ellison, F.O.; Lee, T.H.; Rabalais, J.W., Model for calculating spin-orbit interactions with applications to photoelectron spectroscopy, J. Chem. Phys., 1973, 59, 5342. [all data]

Cox, Evans, et al., 1972
Cox, P.A.; Evans, S.; Orchard, A.F.; Richardson, N.V.; Roberts, P.J., Simple quantitative molecular orbital methods used in connection with photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1972, 54, 26. [all data]

Betteridge, Thompson, et al., 1972
Betteridge, D.; Thompson, M.; Baker, A.D.; Kemp, N.R., Photoelectron spectra of phosphorus halides, alkyl phosphites and phosphates, organophosphorus pesticides, and related compounds, Anal. Chem., 1972, 44, 2005. [all data]


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