Mercury(II) bromide


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-20.42kcal/molReviewChase, 1998Data last reviewed in March, 1962
Quantity Value Units Method Reference Comment
gas,1 bar76.534cal/mol*KReviewChase, 1998Data last reviewed in March, 1962

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 1500. to 6000.
A 14.88740
B 0.014210
C -0.003850
D 0.000328
E -0.043372
F -25.00870
G 94.30270
H -20.42400
ReferenceChase, 1998
Comment Data last reviewed in March, 1962

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
10.560 ± 0.003PILinn, Tzeng, et al., 1983LBLHLM
10.62PEEland, 1970RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Br+15.08 ± 0.18HgBrPILinn, Tzeng, et al., 1983LBLHLM
Br+15.08 ± 0.18HgBrEILinn, Tzeng, et al., 1983LBLHLM
Br+16.7 ± 0.2?EIKiser, Dillard, et al., 1969RDSH
BrHg+11.83 ± 0.03BrPILinn, Tzeng, et al., 1983LBLHLM
BrHg+11.83 ± 0.03BrEILinn, Tzeng, et al., 1983LBLHLM
HgBr+12.09 ± 0.17BrEIKiser, Dillard, et al., 1969RDSH
Br2+12.59 ± 0.03HgPILinn, Tzeng, et al., 1983LBLHLM
Br2+12.59 ± 0.03HgEILinn, Tzeng, et al., 1983LBLHLM
Hg+11.85 ± 0.03Br2EILinn, Tzeng, et al., 1983LBLHLM
Hg+11.85 ± 0.03Br2PILinn, Tzeng, et al., 1983LBLHLM

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Linn, Tzeng, et al., 1983
Linn, S.H.; Tzeng, W.-B.; Brom, J.M., Jr.; Ng, C.Y., Molecular beam photoionization study of HgBr2 and HgI2, J. Chem. Phys., 1983, 78, 50. [all data]

Eland, 1970
Eland, J.H.D., Photoelectron spectra and chemical bonding of mercury(II) compounds, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 37. [all data]

Kiser, Dillard, et al., 1969
Kiser, R.W.; Dillard, J.G.; Dugger, D.L., Mass spectrometry of inorganic halides, Advan. Chem. Ser., 1969, 72, 153. [all data]


Notes

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