thallium bromide
- Formula: BrTl
- Molecular weight: 284.287
- IUPAC Standard InChI: InChI=1S/BrH.Tl/h1H;/q;+1/p-1
- IUPAC Standard InChIKey: PGAPATLGJSQQBU-UHFFFAOYSA-M
- CAS Registry Number: 7789-40-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Thallium monobromide
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Phase change data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
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| Temperature (K) | A | B | C | Reference | Comment |
|---|---|---|---|---|---|
| 763. to 1092. | 4.54661 | 4590.965 | -81.444 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| ~9.0 | PE | Bancroft and Bristow, 1983 | LBLHLM |
| 9.14 ± 0.02 | PI | Berkowitz and Walter, 1968 | RDSH |
| 9.5 | PE | Bancroft and Bristow, 1983 | Vertical value; LBLHLM |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| Tl+ | 6.3 | Br- | PI | Berkowitz and Walter, 1968 | RDSH |
| Tl+ | 9.53 ± 0.02 | Br | PI | Berkowitz and Walter, 1968 | RDSH |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Bancroft and Bristow, 1983
Bancroft, G.M.; Bristow, D.J.,
High resolution HeI and HeII photoelectron spectra of the thallium halides: Valence bands and Tl 5d ligand field splittings,
Can. J. Chem., 1983, 61, 2669. [all data]
Berkowitz and Walter, 1968
Berkowitz, J.; Walter, T.A.,
Photoionization of high-temperature vapors. IV.TIF, TICI, and TIBr,
J. Chem. Phys., 1968, 49, 1184. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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