thallium fluoride
- Formula: FTl
- Molecular weight: 223.3817
- IUPAC Standard InChI: InChI=1S/FH.Tl/h1H;/q;+1/p-1
- IUPAC Standard InChIKey: CULOEOTWMUCRSJ-UHFFFAOYSA-M
- CAS Registry Number: 7789-27-7
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Thallium monofluoride
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.52 | PE | Dehmer, Berkowitz, et al., 1973 | LLK |
| 11.2 ± 0.5 | EI | Murad, Hildenbrand, et al., 1966 | RDSH |
| 10.80 ± 0.02 | PE | Streets and Berkowitz, 1976 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| Tl+ | 10.68 | F | PI | Berkowitz and Walter, 1968 | RDSH |
| Tl+ | 7.59 | F- | PI | Berkowitz and Walter, 1968 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dehmer, Berkowitz, et al., 1973
Dehmer, J.L.; Berkowitz, J.; Cusachs, L.C.,
Photoelectron spectroscopy of high-temperature vapors. III. Monomer and dimer spectra of thallous fluoride,
J. Chem. Phys., 1973, 58, 5681. [all data]
Murad, Hildenbrand, et al., 1966
Murad, E.; Hildenbrand, D.L.; Main, R.P.,
Dissociation energies of group IIIA monofluorides-the possibility of potential maxima in their excited H states,,
J. Chem. Phys., 1966, 45, 263. [all data]
Streets and Berkowitz, 1976
Streets, D.G.; Berkowitz, J.,
The structure of Tl2F2 from photoelectron spectroscopy,
Chem. Phys. Lett., 1976, 38, 475. [all data]
Berkowitz and Walter, 1968
Berkowitz, J.; Walter, T.A.,
Photoionization of high-temperature vapors. IV.TIF, TICI, and TIBr,
J. Chem. Phys., 1968, 49, 1184. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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