Cesium iodide


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Iodide + Cesium iodide = (Iodide • Cesium iodide)

By formula: I- + CsI = (I- • CsI)

Quantity Value Units Method Reference Comment
Δr141.00 ± 0.21kJ/molN/AWang, Wang, et al., 2010gas phase
Δr151. ± 5.4kJ/molN/AGusarov, Gorokhov, et al., 1979gas phase; value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Reference Comment
0.630 ± 0.040Miller, Leopold, et al., 1986Extrapolated by polarizability and radius from experimental data.; B

Ionization energy determinations

IE (eV) Method Reference Comment
7.1PEBenson, Novak, et al., 1987LBLHLM
7.2 ± 0.2EIViswanathan and Hilpert, 1984LBLHLM
6.7 ± 0.4EIEmons, Horlbeck, et al., 1982LBLHLM
7.1 ± 0.1PEPotts and Price, 1977LLK
6.5 ± 0.2PESmith and Pong, 1975LLK
7.1 ± 0.1PEPotts, Williams, et al., 1974LLK
7.10 ± 0.05PEBerkowitz, Dehmer, et al., 1973LLK
7.25 ± 0.05PIBerkowitz, 1969RDSH
7.46 ± 0.05PETimoshenko and Akopyan, 1974Vertical value; LLK
7.2PEGoodman, Allen, et al., 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Cs+7.46 ± 0.05IPIBerkowitz, 1969RDSH
I+14.1 ± 0.3CsEIPlatel, 1965RDSH
Cs+17.60 ± 0.04I(-)PEPotts and Price, 1977Vertical value; LLK
Cs+19.31 ± 0.04I(-)PEPotts and Price, 1977Vertical value; LLK

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wang, Wang, et al., 2010
Wang, Y.L.; Wang, X.B.; Xing, X.P.; Wei, F.; Li, J.; Wang, L.S., Photoelectron Imaging and Spectroscopy of MI2- (M = Cs, Cu, Au): Evolution from Ionic to Covalent Bonding, J. Phys. Chem. A, 2010, 114, 42, 11244-11251, https://doi.org/10.1021/jp103173d . [all data]

Gusarov, Gorokhov, et al., 1979
Gusarov, A.V.; Gorokhov, L.N.; Pyatenko, A.T.; Sidorova, I.V., Negative ions in the vapors of inorganic compounds, Adv. Mass Spectrom., 1979, 8, 262. [all data]

Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C., Electron Affinities of the Alkali Halides and the Structure of their Negative Ions, J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091 . [all data]

Benson, Novak, et al., 1987
Benson, J.M.; Novak, I.; Potts, A.W., Photoelectron spectroscopy of the caesium halides using synchrotron radiation, J. Phys. B:, 1987, 20, 6257. [all data]

Viswanathan and Hilpert, 1984
Viswanathan, R.; Hilpert, K., Mass spectrometric study of the vaporization of cesium iodide and thermochemistry of (CsI)2(g) and (CsI)3(g), Ber. Bunsen-Ges. Phys. Chem., 1984, 88, 125. [all data]

Emons, Horlbeck, et al., 1982
Emons, H.-H.; Horlbeck, W.; Kiessling, D., Massenspektrometrische untersuchung der gasphase uber alkalimetalliodiden, Z. Anorg. Allg. Chem., 1982, 488, 212. [all data]

Potts and Price, 1977
Potts, A.W.; Price, W.C., Photoelectron studies of ionic materials using molecular beam techniques, Phys. Scr., 1977, 16, 191. [all data]

Smith and Pong, 1975
Smith, J.A.; Pong, W., Ultraviolet photoelectron spectra of cesium halides, Phys. Rev. B:, 1975, 12, 5931. [all data]

Potts, Williams, et al., 1974
Potts, A.W.; Williams, T.A.; Price, W.C., Photoelectron spectra and electronic structure of diatomic alkali halides, Proc. Roy. Soc. London A, 1974, 341, 147. [all data]

Berkowitz, Dehmer, et al., 1973
Berkowitz, J.; Dehmer, J.L.; Walker, T.E.H., PES of high-temperature vapors. IV. The cesium halides. Effect of spin-orbit interaction on the photoelectron and mass spectra of the alkali halides, J. Chem. Phys., 1973, 59, 3645. [all data]

Berkowitz, 1969
Berkowitz, J., Photoionization of high-temperature vapors. V. Cesium halides; chemical shift of autoionization, J. Chem. Phys., 1969, 50, 3503. [all data]

Timoshenko and Akopyan, 1974
Timoshenko, M.M.; Akopyan, M.E., Photoelectron spectra of cesium halides, High Energy Chem., 1974, 8, 175, In original 211. [all data]

Goodman, Allen, et al., 1974
Goodman, T.D.; Allen, J.D., Jr.; Cusachs, L.C.; Schweitzer, G.K., The photoelectron spectra of gaseous alkali halides, J. Electron Spectrosc. Relat. Phenom., 1974, 3, 289. [all data]

Platel, 1965
Platel, G., Mesures des potentials d'apparition des ions obtenus par impact electronique dans la phase vapeur des iodures alcalins et des melanges LiI-MI, J. Chim. Phys., 1965, 62, 1176. [all data]


Notes

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