chromium trifluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
12.5 ± 0.3EIMalkerova, Alikhanyan, et al., 1979LLK
12.2 ± 0.3EIZmbov and Margrave, 1967RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Cr+20.1 ± 0.3?EIZmbov and Margrave, 1967RDSH
CrF+14.0 ± 0.3?EIZmbov and Margrave, 1967RDSH
F2Cr+14.8 ± 0.5FEIMalkerova, Alikhanyan, et al., 1979LLK
CrF2+13.5 ± 0.3FEIZmbov and Margrave, 1967RDSH

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + CrF3 = (Fluorine anion • CrF3)

By formula: F- + CrF3 = (F- • CrF3)

Quantity Value Units Method Reference Comment
Δr387. ± 15.kJ/molTDEqBoltalina, Borshchevskii, et al., 1991gas phase; Data at 0 K. See also Pramann and Rademann, 1999; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Malkerova, Alikhanyan, et al., 1979
Malkerova, I.P.; Alikhanyan, A.S.; Pervov, V.S.; Tripol'skaya, T.A.; Gorgoraki, V.I.; Malyusov, V.A., High-temperature investigations of chromium lower fluorides, Russ. J. Inorg. Chem., 1979, 24, 1775. [all data]

Zmbov and Margrave, 1967
Zmbov, K.F.; Margrave, J.L., Mass spectrometric studies at high temperatures. XV.Sublimation pressures of chromium, manganese and iron trifluoridcs and the heat of dissociation of Fe,F,(g), J. Inorg. Nucl. Chem., 1967, 29, 673. [all data]

Boltalina, Borshchevskii, et al., 1991
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of Chromium Gaseous Fluorides and Their Negative Ions, Zh. Fiz. Khim. SSSR, 1991, 65, 884. [all data]

Pramann and Rademann, 1999
Pramann, A.; Rademann, K., Mass-spectrometric study of formation and stability of manganese and manganese oxide cluster anions, Int. J. Mass Spectrom., 1999, 187, 673-683, https://doi.org/10.1016/S1387-3806(98)14197-0 . [all data]


Notes

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