pentafluoroarsorane


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
15.0PERunger, 1985LBLHLM
15.53PERunger, 1985Vertical value; LBLHLM

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
AsF+23.8 ± 0.2?EIPabst, Sharpe, et al., 1980LLK
AsF2+15.8 ± 0.2?EIPabst, Sharpe, et al., 1980LLK
AsF3+14.0 ± 0.1F2(-)EIPabst, Sharpe, et al., 1980LLK
AsF4+13.8 ± 0.2F(-)EIPabst, Sharpe, et al., 1980LLK
F+22.1 ± 0.2AsF4EIPabst, Sharpe, et al., 1980LLK

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   D3h     Symmetry Number σ = 6


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a1' 1 AsF3 s-str 734  C 734.3 VS p gas
a1' 2 AsF2 s-str 644  C 644 M gas
a2 3 AsF2 a-str 787  B 787.4 VS gas
a2 4 AsF3 op-deform 400  B 400.4 S gas
e' 5 AsF3 d-str 811  B 811.4 VS gas 813 M dp gas
e' 6 AsF3 d-deform 372  C 372 S gas 366 liq.
e' 7 AsF bend 123  C 123 W gas 130 M dp gas
e 8 AsF bend 386  C 386 M dp gas

Source: Shimanouchi, 1972

Notes

VSVery strong
SStrong
MMedium
WWeak
pPolarized
dpDepolarized
B1~3 cm-1 uncertainty
C3~6 cm-1 uncertainty

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Runger, 1985
Runger, G., Title unavailable, Ph.D. Thesis for Univ. of Hamburg, 1985. [all data]

Pabst, Sharpe, et al., 1980
Pabst, R.E.; Sharpe, M.C.; Margrave, J.L.; Franklin, J.L., An electron impact study of the appearance energies of positive ions from AsF3, AsCl3, AsBr3 and AsF5, Int. J. Mass Spectrom. Ion Phys., 1980, 33, 187. [all data]

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume II, J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]


Notes

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