Silver chloride

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C2Ag2 (cr) + 2(Hydrogen chloride • 12.3Water) (solution) = Acetylene (aq) + 2Silver chloride (cr)

By formula: C2Ag2 (cr) + 2(HCl • 12.3H2O) (solution) = C2H2 (aq) + 2AgCl (cr)

Quantity Value Units Method Reference Comment
Δr-18.6 ± 0.1kcal/molRSCFinch, Gardner, et al., 1991 

Gas phase ion energetics data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to AgCl+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
11.3 ± 0.5EIWagner and Grimley, 1972LLK
10.8 ± 0.4EIGraber and Weil, 1972LLK
10.3 ± 0.4EIVisnapuu and Jensen, 1970RDSH
10.5 ± 0.3EIHildenbrand, 1970RDSH
10.08PEBerkowitz, Batson, et al., 1980Vertical value; LLK
10.14PEBerkowitz, Batson, et al., 1980Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Ag+11.1 ± 0.3?EIGraber and Weil, 1972LLK
Ag+11.0 ± 0.4ClEIVisnapuu and Jensen, 1970RDSH

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Finch, Gardner, et al., 1991
Finch, A.; Gardner, P.J.; Head, A.J.; Majdi, H.S., Thermochim. Acta, 1991, 180, 325. [all data]

Wagner and Grimley, 1972
Wagner, L.C.; Grimley, R.T., A study of ionization processes by the angular distribution technique. The AgCl system, J. Phys. Chem., 1972, 76, 2819. [all data]

Graber and Weil, 1972
Graber, P.; Weil, K.G., Mass spectrometric investigations of silver halides I: mass spectrum, appearance potentials, fragmentation scheme of silver chloride, Ber. Bunsen-Ges. Phys. Chem., 1972, 76, 410. [all data]

Visnapuu and Jensen, 1970
Visnapuu, A.; Jensen, J.W., Composition and properties of vapors over molten silver chloride, J.Less-Common Metals, 1970, 20, 141. [all data]

Hildenbrand, 1970
Hildenbrand, D.L., Dissociation energies and chemical bonding in the alkaline-earth chlorides from mass spectrometric studies, J. Chem. Phys., 1970, 52, 5751. [all data]

Berkowitz, Batson, et al., 1980
Berkowitz, J.; Batson, C.H.; Goodman, G.L., Photoelectron spectroscopy of AgCl, AgBr, and AgI vapors, J. Chem. Phys., 1980, 72, 5829. [all data]


Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References