iodine pentafluoride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil371.KN/APCR Inc., 1990BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Reference Comment
39.3330.Osborne, 1971Based on data from 283. to 378. K.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
12.943 ± 0.005PEDeKock, Higginson, et al., 1972LLK
13.5 ± 0.2EIIrsa and Friedman, 1958RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
IF+~24.?EIIrsa and Friedman, 1958RDSH
IF2+15.1 ± 0.3?EIIrsa and Friedman, 1958RDSH
IF3+11.5 ± 0.3?EIIrsa and Friedman, 1958RDSH
IF4+13.6 ± 0.3F-?EIIrsa and Friedman, 1958RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Osborne, 1971
Osborne, Darrell W., Calorimetric Study of Iodine Pentafluoride: Heat Capacity between 5 and 350°K, Enthalpy of Fusion and Vaporization, Standard Entropy of the Vapor, and Other Thermodynamic Properties, J. Chem. Phys., 1971, 54, 9, 3790, https://doi.org/10.1063/1.1675430 . [all data]

DeKock, Higginson, et al., 1972
DeKock, R.L.; Higginson, B.R.; Lloyd, D.R., Photoelectron spectra of halides. Part 6.--The spectra of SF5Cl, BrF5 and IF5, Faraday Discuss. Chem. Soc., 1972, 54, 84. [all data]

Irsa and Friedman, 1958
Irsa, A.P.; Friedman, L., Mass spectra of halogen fluorides, J. Inorg. Nucl. Chem., 1958, 6, 77. [all data]


Notes

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