zirconium tetrafluoride


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-400.000kcal/molReviewChase, 1998Data last reviewed in June, 1975
Quantity Value Units Method Reference Comment
gas,1 bar76.336cal/mol*KReviewChase, 1998Data last reviewed in June, 1975

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 6000.
A 24.95619
B 0.742436
C -0.200215
D 0.017034
E -0.391898
F -408.7861
G 104.1200
H -400.0000
ReferenceChase, 1998
Comment Data last reviewed in June, 1975

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfsolid-456.800kcal/molReviewChase, 1998Data last reviewed in June, 1975
Quantity Value Units Method Reference Comment
solid25.014cal/mol*KReviewChase, 1998Data last reviewed in June, 1975

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1400.
A 25.74790
B 11.24780
C -6.878860
D 2.273001
E -0.338087
F -466.0581
G 51.20471
H -456.8000
ReferenceChase, 1998
Comment Data last reviewed in June, 1975

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub57. ± 2.kcal/molAVGN/AAverage of 7 values; Individual data points

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Fluorine anion + zirconium tetrafluoride = (Fluorine anion • zirconium tetrafluoride)

By formula: F- + F4Zr = (F- • F4Zr)

Quantity Value Units Method Reference Comment
Δr99.3 ± 2.0kcal/molTDEqSkokan, Sorokin, et al., 1982gas phase; Fluoride Affinity: 22±1 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention
Δr96.3 ± 1.0kcal/molTDEqSkokan, Nikitin, et al., 1981gas phase; Fluoride Affinity: 23.12 kcal < AlF3; value altered from reference due to conversion from electron convention to ion convention

F5Zr- + zirconium tetrafluoride = F9Zr2-

By formula: F5Zr- + F4Zr = F9Zr2-

Quantity Value Units Method Reference Comment
Δr51.2 ± 1.0kcal/molTDAsSkokan, Sorokin, et al., 1982gas phase; value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
ZrF+29.4 ± 0.5?EIMurad and Hildenbrand, 1966 
ZrF2+23.4 ± 0.5?EIMurad and Hildenbrand, 1966 
ZrF3+14.5 ± 0.5FEIMurad and Hildenbrand, 1966 
Zr+29.5 ± 0.5?EIMurad and Hildenbrand, 1966 

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Skokan, Sorokin, et al., 1982
Skokan, E.V.; Sorokin, I.D.; Sidorov, L.N.; Nikitin, M.I., Mass Spectrometric Determination of the Enthalpies of Dissociation of Gaseous Complex Fluorides into Neutral and Charged Particles. VI. Enthalpy of Formation of ZrF5-, Int. J. Mass Spectrom. Ion Phys., 1982, 43, 4, 209, https://doi.org/10.1016/0020-7381(82)80017-X . [all data]

Skokan, Nikitin, et al., 1981
Skokan, E.V.; Nikitin, M.I.; Sorokin, I.D.; Gusarov, A.V.; Sidirov, L.N., Determination of the heat of formation of the tetrafluoroscandate and pentfluorozirconate ions by the effusion nethod, Russ. J. Phys. Chem., 1981, 55, 1062. [all data]

Murad and Hildenbrand, 1966
Murad, E.; Hildenbrand, D.L., Mass-spectrometric study of the thermodynamic properties of Zr-F species, J. Chem. Phys., 1966, 45, 4751. [all data]


Notes

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