manganese trifluoride
- Formula: F3Mn
- Molecular weight: 111.933255
- CAS Registry Number: 7783-53-1
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to F3Mn+ (ion structure unspecified)
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 12.6 ± 0.2 | EI | Ehlert and Hsia, 1973 | LLK |
| 12. ± 0.8 | EI | Zmbov and Margrave, 1967 | RDSH |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| MnF+ | 14.2 ± 0.3 | ? | EI | Zmbov and Margrave, 1967 | RDSH |
| F2Mn+ | 14.8 ± 0.2 | ? | EI | Ehlert and Hsia, 1973 | LLK |
| MnF2+ | 13.7 ± 0.3 | F | EI | Zmbov and Margrave, 1967 | RDSH |
| Mn+ | 19.5 ± 0.5 | ? | EI | Zmbov and Margrave, 1967 | RDSH |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ehlert and Hsia, 1973
Ehlert, T.C.; Hsia, M.,
Mass spectrometric and thermochemical studies of the manganese fluorides,
J. Fluorine Chem., 1973, 2, 33. [all data]
Zmbov and Margrave, 1967
Zmbov, K.F.; Margrave, J.L.,
Mass spectrometric studies at high temperatures. XV.Sublimation pressures of chromium, manganese and iron trifluoridcs and the heat of dissociation of Fe,F,(g),
J. Inorg. Nucl. Chem., 1967, 29, 673. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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