zinc fluoride


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
60.331015.MEBiefeld and Eick, 1973Based on data from 901. to 1125. K.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Fluorine anion + F2Zn = (Fluorine anion • F2Zn)

By formula: F- + F2Zn = (F- • F2Zn)

Quantity Value Units Method Reference Comment
Δr80.5 ± 4.5kcal/molTDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
13.91 ± 0.03PELee, Law, et al., 1980 
13.5PEDyke, Fayad, et al., 1980 
13.91PEDyke, Fayad, et al., 1980Vertical value

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + F2Zn = (Fluorine anion • F2Zn)

By formula: F- + F2Zn = (F- • F2Zn)

Quantity Value Units Method Reference Comment
Δr80.5 ± 4.5kcal/molTDAsBoltalina, Borshchevskii, et al., 1992gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Biefeld and Eick, 1973
Biefeld, Robert M.; Eick, Harry A., The sublimation thermodynamics of zinc(II) fluoride, The Journal of Chemical Thermodynamics, 1973, 5, 3, 353-360, https://doi.org/10.1016/S0021-9614(73)80024-2 . [all data]

Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N., Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase, Russ. J. Phys. Chem., 1992, 66, 1223. [all data]

Lee, Law, et al., 1980
Lee, E.P.F.; Law, D.; Potts, A.W., Photoelectron spectra and valence shell electronic structure of zinc and cadmium difluoride, J. Chem. Soc. Faraday Trans. 2, 1980, 76, 1314. [all data]

Dyke, Fayad, et al., 1980
Dyke, J.M.; Fayad, N.K.; Josland, G.D.; Morris, A., Study by high-temperature photoelectron spectroscopy of the electronic structure of the transition metal difluorides, CuF2 and ZnF2, J. Chem. Soc. Faraday Trans. 2, 1980, 76, 1672. [all data]


Notes

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