zinc fluoride
- Formula: F2Zn
- Molecular weight: 103.38
- CAS Registry Number: 7783-49-5
- Information on this page:
- Data at other public NIST sites:
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Phase change data
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
60.33 | 1015. | ME | Biefeld and Eick, 1973 | Based on data from 901. to 1125. K. |
Reaction thermochemistry data
Go To: Top, Phase change data, Gas phase ion energetics data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: F- + F2Zn = (F- • F2Zn)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 80.5 ± 4.5 | kcal/mol | TDAs | Boltalina, Borshchevskii, et al., 1992 | gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention |
Gas phase ion energetics data
Go To: Top, Phase change data, Reaction thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
13.91 ± 0.03 | PE | Lee, Law, et al., 1980 | |
13.5 | PE | Dyke, Fayad, et al., 1980 | |
13.91 | PE | Dyke, Fayad, et al., 1980 | Vertical value |
Ion clustering data
Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: F- + F2Zn = (F- • F2Zn)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 80.5 ± 4.5 | kcal/mol | TDAs | Boltalina, Borshchevskii, et al., 1992 | gas phase; Critical review; value altered from reference due to conversion from electron convention to ion convention |
References
Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Biefeld and Eick, 1973
Biefeld, Robert M.; Eick, Harry A.,
The sublimation thermodynamics of zinc(II) fluoride,
The Journal of Chemical Thermodynamics, 1973, 5, 3, 353-360, https://doi.org/10.1016/S0021-9614(73)80024-2
. [all data]
Boltalina, Borshchevskii, et al., 1992
Boltalina, O.V.; Borshchevskii, A.Y.; Sidorov, L.N.,
Thermochemistry of 3d Elements Fluorides and Their Negative Ions in Gas Phase,
Russ. J. Phys. Chem., 1992, 66, 1223. [all data]
Lee, Law, et al., 1980
Lee, E.P.F.; Law, D.; Potts, A.W.,
Photoelectron spectra and valence shell electronic structure of zinc and cadmium difluoride,
J. Chem. Soc. Faraday Trans. 2, 1980, 76, 1314. [all data]
Dyke, Fayad, et al., 1980
Dyke, J.M.; Fayad, N.K.; Josland, G.D.; Morris, A.,
Study by high-temperature photoelectron spectroscopy of the electronic structure of the transition metal difluorides, CuF2 and ZnF2,
J. Chem. Soc. Faraday Trans. 2, 1980, 76, 1672. [all data]
Notes
Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔsubH Enthalpy of sublimation - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.