Oxygen difluoride

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas24.52kJ/molReviewChase, 1998Data last reviewed in September, 1995
Quantity Value Units Method Reference Comment
gas,1 bar247.46J/mol*KReviewChase, 1998Data last reviewed in September, 1995

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 600.600. to 6000.
A 15.0697657.26808
B 136.26120.640466
C -172.8088-0.150702
D 81.407670.011677
E 0.071893-1.898625
F 15.575531.585041
G 232.4333307.3976
H 24.5180324.51803
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in September, 1995 Data last reviewed in September, 1995

Phase change data

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tboil127.9KN/AStreng, 1971Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Tfus49.4KN/AStreng, 1971Uncertainty assigned by TRC = 0.25 K; TRC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
77.0 to 128.55.26568758.40115.742Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Quantity Value Units Method Reference Comment
IE (evaluated)13.11 ± 0.01eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
13.11 ± 0.01PIBerkowitz, Dehmer, et al., 1973LLK
13.11PEBrundle, Robin, et al., 1972LLK
13.13PECornford, Frost, et al., 1971LLK
13.26PEChadwick, Cornford, et al., 1972Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
OF+≤14.438FPIBerkowitz, Dehmer, et al., 1973LLK
OF+15.8 ± 0.2FEIMalone and McGee, 1965RDSH
OF+15.8 ± 0.2FEIDibeler, Reese, et al., 1957RDSH

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Streng, 1971
Streng, A.G., Miscibility and Compatibility of Some Liquid and Solidified Gases at Low Temperature, J. Chem. Eng. Data, 1971, 16, 357. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Berkowitz, Dehmer, et al., 1973
Berkowitz, J.; Dehmer, P.M.; Chupka, W.A., Photoionization mass spectrometry of F2O, J. Chem. Phys., 1973, 59, 925. [all data]

Brundle, Robin, et al., 1972
Brundle, C.R.; Robin, M.B.; Kuebler, N.A.; Basch, H., Perfluoro effect in photoelectron spectroscopy. I. Nonaromatic molecules, J. Am. Chem. Soc., 1972, 94, 1451. [all data]

Cornford, Frost, et al., 1971
Cornford, A.B.; Frost, D.C.; Herring, F.G.; McDowell, C.A., Photoelectron spectra of F2O and Cl2O, J. Chem. Phys., 1971, 55, 2820. [all data]

Chadwick, Cornford, et al., 1972
Chadwick, D.; Cornford, A.B.; Frost, D.C.; Herring, F.G.; Katrib, A.; McDowell, C.A.; McLean, R.A.N., Photoelectron spectra of some dihalocompounds in Electron spectroscopy, ed. D.A. Shirley (North-Holland Publixhing Co, Amsterdam), 1972, 453. [all data]

Malone and McGee, 1965
Malone, T.J.; McGee, H.A., Jr., Mass spectrometric investigations of the synthesis, stability, and energetics of the low-temperature oxygen fluorides. I. Dioxygen difluoride, J. Phys. Chem., 1965, 69, 4338. [all data]

Dibeler, Reese, et al., 1957
Dibeler, V.H.; Reese, R.M.; Franklin, J.L., Ionization and dissociation of oxygen difluoride by electron impact, J. Chem. Phys., 1957, 27, 1296. [all data]


Notes

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