Magnesium fluoride
- Formula: F2Mg
- Molecular weight: 62.3018
- IUPAC Standard InChI: InChI=1S/2FH.Mg/h2*1H;/q;;+2/p-2
- IUPAC Standard InChIKey: ORUIBWPALBXDOA-UHFFFAOYSA-L
- CAS Registry Number: 7783-40-6
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| IE (evaluated) | 13.6 ± 0.3 | eV | N/A | N/A | L |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 13.3 ± 0.3 | EI | Hildenbrand, 1968 | RDSH |
| 14.0 ± 0.5 | EI | Murad, Hildenbrand, et al., 1966 | RDSH |
| 13.5 ± 0.4 | EI | Berkowitz and Marquart, 1962 | RDSH |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| MgF+ | 13.5 ± 1.0 | F | EI | Hildenbrand, 1968 | RDSH |
| MgF+ | 13.7 ± 0.4 | F | EI | Ehlert, Blue, et al., 1964 | RDSH |
| MgF+ | 13.5 ± 0.4 | F | EI | Berkowitz and Marquart, 1962 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hildenbrand, 1968
Hildenbrand, D.L.,
Mass-spectrometric studies of bonding in the group IIA fluorides,
J. Chem. Phys., 1968, 48, 3657. [all data]
Murad, Hildenbrand, et al., 1966
Murad, E.; Hildenbrand, D.L.; Main, R.P.,
Dissociation energies of group IIIA monofluorides-the possibility of potential maxima in their excited H states,,
J. Chem. Phys., 1966, 45, 263. [all data]
Berkowitz and Marquart, 1962
Berkowitz, J.; Marquart, J.R.,
Mass-spectrometric study of the magnesium halides,
J. Chem. Phys., 1962, 37, 1853. [all data]
Ehlert, Blue, et al., 1964
Ehlert, T.C.; Blue, G.D.; Green, J.W.; Margrave, J.L.,
Mass spectrometric studies at high temperatures. IV. Dissociation energies of the alkaline earth monofluorides,
J. Chem. Phys., 1964, 41, 2250. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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