dihydrogen selenide


Phase change data

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Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
157.8 to 232.13.61665596.484-66.353Stull, 1947Coefficents calculated by NIST from author's data.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

HSe- + Hydrogen cation = dihydrogen selenide

By formula: HSe- + H+ = H2Se

Quantity Value Units Method Reference Comment
Δr1428.8 ± 2.9kJ/molD-EAStoneman and Larson, 1986gas phase; Wagman, Evans, et al., 1982 ΔHf(AH) = 7.1 kcal/mol
Δr1434. ± 38.kJ/molG+TSDixon, Holtz, et al., 1972gas phase; Between H2S, HCl; value altered from reference due to change in acidity scale
Δr1424.7kJ/molN/ACheck, Faust, et al., 2001gas phase; MnO-(t); ; ΔS(EA)=5.5
Quantity Value Units Method Reference Comment
Δr1402.4 ± 3.3kJ/molH-TSStoneman and Larson, 1986gas phase; Wagman, Evans, et al., 1982 ΔHf(AH) = 7.1 kcal/mol
Δr1407. ± 38.kJ/molIMRBDixon, Holtz, et al., 1972gas phase; Between H2S, HCl; value altered from reference due to change in acidity scale
Δr1398.3kJ/molN/ACheck, Faust, et al., 2001gas phase; MnO-(t); ; ΔS(EA)=5.5

Nitrogen oxide anion + dihydrogen selenide = (Nitrogen oxide anion • dihydrogen selenide)

By formula: NO2- + H2Se = (NO2- • H2Se)

Quantity Value Units Method Reference Comment
Δr87.4 ± 4.2kJ/molTDEqWlodek, Luczynski, et al., 1983gas phase; Equilibration with SO2..NO2-
Quantity Value Units Method Reference Comment
Δr43. ± 15.kJ/molTDEqWlodek, Luczynski, et al., 1983gas phase; Equilibration with SO2..NO2-

(Nitrogen oxide anion • 2dihydrogen selenide) + dihydrogen selenide = (Nitrogen oxide anion • 3dihydrogen selenide)

By formula: (NO2- • 2H2Se) + H2Se = (NO2- • 3H2Se)

Quantity Value Units Method Reference Comment
Δr30.5 ± 2.9kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase
Quantity Value Units Method Reference Comment
Δr13.0 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase

(NO3 anion • dihydrogen selenide) + dihydrogen selenide = (NO3 anion • 2dihydrogen selenide)

By formula: (NO3- • H2Se) + H2Se = (NO3- • 2H2Se)

Quantity Value Units Method Reference Comment
Δr30.1 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase
Quantity Value Units Method Reference Comment
Δr19.2 ± 2.9kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase

(Nitrogen oxide anion • dihydrogen selenide) + dihydrogen selenide = (Nitrogen oxide anion • 2dihydrogen selenide)

By formula: (NO2- • H2Se) + H2Se = (NO2- • 2H2Se)

Quantity Value Units Method Reference Comment
Δr35.6 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase
Quantity Value Units Method Reference Comment
Δr19.7 ± 1.3kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase

NO3 anion + dihydrogen selenide = (NO3 anion • dihydrogen selenide)

By formula: NO3- + H2Se = (NO3- • H2Se)

Quantity Value Units Method Reference Comment
Δr72.0 ± 2.5kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase
Quantity Value Units Method Reference Comment
Δr31.8 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference
0.0841900.LN/A

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to H2Se+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)9.892 ± 0.005eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)707.8kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity676.4kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
9.886 ± 0.003PIGibson, Greene, et al., 1986LBLHLM
9.897 ± 0.002TEBorlin, Jungen, et al., 1986LBLHLM
10.00 ± 0.05EIBalkis, Gaines, et al., 1976LLK
9.93PENatalis, 1973LLK
9.88PEPotts and Price, 1972LLK
9.93PEDelwiche, Natalis, et al., 1970RDSH
9.882 ± 0.001SPrice, Teegan, et al., 1950RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
HSe+13.266 ± 0.007HPIGibson, Greene, et al., 1986LBLHLM
HSe+13.6 ± 0.2HEIBalkis, Gaines, et al., 1976LLK
HSe+13.8 ± 0.2HEIDixon, Holtz, et al., 1972LLK
Se+11.916 ± 0.006H2PIGibson, Greene, et al., 1986LBLHLM
Se+12.6 ± 0.1?EIDixon, Holtz, et al., 1972LLK

De-protonation reactions

HSe- + Hydrogen cation = dihydrogen selenide

By formula: HSe- + H+ = H2Se

Quantity Value Units Method Reference Comment
Δr1428.8 ± 2.9kJ/molD-EAStoneman and Larson, 1986gas phase; Wagman, Evans, et al., 1982 ΔHf(AH) = 7.1 kcal/mol; B
Δr1434. ± 38.kJ/molG+TSDixon, Holtz, et al., 1972gas phase; Between H2S, HCl; value altered from reference due to change in acidity scale; B
Δr1424.7kJ/molN/ACheck, Faust, et al., 2001gas phase; MnO-(t); ; ΔS(EA)=5.5; B
Quantity Value Units Method Reference Comment
Δr1402.4 ± 3.3kJ/molH-TSStoneman and Larson, 1986gas phase; Wagman, Evans, et al., 1982 ΔHf(AH) = 7.1 kcal/mol; B
Δr1407. ± 38.kJ/molIMRBDixon, Holtz, et al., 1972gas phase; Between H2S, HCl; value altered from reference due to change in acidity scale; B
Δr1398.3kJ/molN/ACheck, Faust, et al., 2001gas phase; MnO-(t); ; ΔS(EA)=5.5; B

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Nitrogen oxide anion + dihydrogen selenide = (Nitrogen oxide anion • dihydrogen selenide)

By formula: NO2- + H2Se = (NO2- • H2Se)

Quantity Value Units Method Reference Comment
Δr87.4 ± 4.2kJ/molTDEqWlodek, Luczynski, et al., 1983gas phase; Equilibration with SO2..NO2-
Quantity Value Units Method Reference Comment
Δr43. ± 15.kJ/molTDEqWlodek, Luczynski, et al., 1983gas phase; Equilibration with SO2..NO2-

(Nitrogen oxide anion • dihydrogen selenide) + dihydrogen selenide = (Nitrogen oxide anion • 2dihydrogen selenide)

By formula: (NO2- • H2Se) + H2Se = (NO2- • 2H2Se)

Quantity Value Units Method Reference Comment
Δr35.6 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase
Quantity Value Units Method Reference Comment
Δr19.7 ± 1.3kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase

(Nitrogen oxide anion • 2dihydrogen selenide) + dihydrogen selenide = (Nitrogen oxide anion • 3dihydrogen selenide)

By formula: (NO2- • 2H2Se) + H2Se = (NO2- • 3H2Se)

Quantity Value Units Method Reference Comment
Δr30.5 ± 2.9kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase
Quantity Value Units Method Reference Comment
Δr13.0 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase

NO3 anion + dihydrogen selenide = (NO3 anion • dihydrogen selenide)

By formula: NO3- + H2Se = (NO3- • H2Se)

Quantity Value Units Method Reference Comment
Δr72.0 ± 2.5kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase
Quantity Value Units Method Reference Comment
Δr31.8 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase

(NO3 anion • dihydrogen selenide) + dihydrogen selenide = (NO3 anion • 2dihydrogen selenide)

By formula: (NO3- • H2Se) + H2Se = (NO3- • 2H2Se)

Quantity Value Units Method Reference Comment
Δr30.1 ± 2.1kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase
Quantity Value Units Method Reference Comment
Δr19.2 ± 2.9kJ/molTDAsWlodek, Luczynski, et al., 1983gas phase

References

Go To: Top, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Stoneman and Larson, 1986
Stoneman, R.C.; Larson, D.J., Photodetachment spectroscopy of SeH- in a magnetic field, J. Phys. B:, 1986, 19, 405. [all data]

Wagman, Evans, et al., 1982
Wagman, D.D.; Evans, W.H.; Parker, V.B.; Schumm, R.H.; Halow, I.; Bailey, S.M.; Churney, K.L.; Nuttall, R.L., The NBS Tables of Chemical Thermodynamic Properties (NBS Tech Note 270), J. Phys. Chem. Ref. Data, Supl. 1, 1982, 11. [all data]

Dixon, Holtz, et al., 1972
Dixon, D.A.; Holtz, D.; Beauchamp, J.L., Acidity, basicity, and gas-phase ion chemistry of hydrogen selenide by ion cyclotron resonance spectroscopy, Inorg. Chem., 1972, 11, 960. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Wlodek, Luczynski, et al., 1983
Wlodek, S.; Luczynski, Z.; Wincel, H., Gas - Phase Solvation of NO2- and NO3- by Ethyl Nitrate, Int. J. Mass Spectrom. Ion Phys., 1983, 52, 2-3, 149, https://doi.org/10.1016/0020-7381(83)85036-0 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Gibson, Greene, et al., 1986
Gibson, S.T.; Greene, J.P.; Berkowitz, J., A photoionization study of SeH and H2Se, J. Chem. Phys., 1986, 85, 4815. [all data]

Borlin, Jungen, et al., 1986
Borlin, K.; Jungen, M.; Karlsson, L.; Maripuu, R., Photoionization of H2Se: High-resolution and threshold photoelectron spectra, Chem. Phys., 1986, 113, 309. [all data]

Balkis, Gaines, et al., 1976
Balkis, T.; Gaines, A.F.; Ozgen, G.; Ozgen, I.T.; Flowers, M.C., Ionization of hydrogen sul- phide, selenide and telluride by electron impact, J. Chem. Soc. Faraday Trans. 2, 1976, 72, 524. [all data]

Natalis, 1973
Natalis, P., Contribution a la spectroscopie photoelectronique. Effets de l'autoionisation dans less spectres photoelectroniques de molecules diatomiques et triatomiques, Acad. R. Belg. Mem. Cl. Sci. Collect. 8, 1973, 41, 1. [all data]

Potts and Price, 1972
Potts, A.W.; Price, W.C., Photoelectron spectra and valence shell orbital structures of groups V VI hydrides, Proc. R. Soc. London A:, 1972, 326, 181. [all data]

Delwiche, Natalis, et al., 1970
Delwiche, J.; Natalis, P.; Collin, J.E., High resolution photoelectron spectrometry of H2S and H2Se, Intern. J. Mass Spectrom. Ion Phys., 1970, 5, 443. [all data]

Price, Teegan, et al., 1950
Price, W.C.; Teegan, J.P.; Walsh, A.D., The far ultra-violet absorption spectra of the hydrides and deuterides of sulphur, selenium and tellurium and of the methyl derivatives of hydrogen sulphide, Proc. Roy. Soc. (London), 1950, A201, 600. [all data]


Notes

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