Hydrogen sulfide
- Formula: H2S
- Molecular weight: 34.081
- IUPAC Standard InChIKey: RWSOTUBLDIXVET-UHFFFAOYSA-N
- CAS Registry Number: 7783-06-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Dihydrogen monosulfide; Dihydrogen sulfide; Hydrosulfuric acid; Stink damp; Sulfur hydride; Sulfureted hydrogen; H2S; Sulfuretted hydrogen; Hydrogen sulphide; Hydrogen sulfide (H2S); Acide sulfhydrique; Hydrogene sulfure; Idrogeno solforato; Rcra waste number U135; Schwefelwasserstoff; Siarkowodor; UN 1053; Zwavelwaterstof; Hepatic gas; Hepatic acid; Hydrogen monosulfide; Sewer gas
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Gas phase ion energetics data
Go To: Top, Ion clustering data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias
Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to H2S+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 10.457 ± 0.012 | eV | N/A | N/A | L |
Quantity | Value | Units | Method | Reference | Comment |
Proton affinity (review) | 168. | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 161.0 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
HS+ | 14.300 ± 0.024 | H | PI | Prest, Tzeng, et al., 1983 | LBLHLM |
HS+ | 14.7 ± 0.2 | H | EI | Balkis, Gaines, et al., 1976 | LLK |
HS+ | 14.4 | H | EI | Morrison and Traeger, 1973 | LLK |
HS+ | 14.27 ± 0.02 | H | PI | Dibeler and Liston, 1968 | RDSH |
HS+ | 14.4 ± 0.1 | H | EI | Palmer and Lossing, 1962 | RDSH |
S+ | 13.375 ± 0.022 | H2 | PI | Prest, Tzeng, et al., 1983 | LBLHLM |
S+ | 13.41 | H2 | PIPECO | Eland, 1979 | LLK |
S+ | 13.5 | H2 | EI | Morrison and Traeger, 1973 | LLK |
S+ | 13.36 ± 0.01 | H2 | PI | Dibeler and Liston, 1968 | RDSH |
S+ | 13.40 ± 0.01 | H2 | PI | Dibeler and Liston, 1968 | RDSH |
De-protonation reactions
HS- + =
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 351.4 ± 0.7 | kcal/mol | AVG | N/A | Average of 6 out of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 344.4 ± 3.0 | kcal/mol | H-TS | Rempala and Ervin, 2000 | gas phase; B |
ΔrG° | 344.8 ± 2.0 | kcal/mol | IMRE | Bartmess, Scott, et al., 1979 | gas phase; value altered from reference due to change in acidity scale; B |
ΔrG° | 344.90 ± 0.10 | kcal/mol | H-TS | Shiell, Hu, et al., 1900 | gas phase; 0K:350.125±0.009 kcal/mol, corr to 298K from Gurvich, Veyts, et al., With EA( Breyer, Frey, et al., 1981)BDE(0K)=89.97±0.05; B |
ΔrG° | 345.6 ± 2.0 | kcal/mol | IMRE | Cumming and Kebarle, 1978 | gas phase; B |
ΔrG° | 342.30 | kcal/mol | N/A | Check, Faust, et al., 2001 | gas phase; MnO2-(t); ; ΔS(EA)=5.4; B |
Ion clustering data
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: CH6N+ + H2S = (CH6N+ • H2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.8 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20. | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
5.4 | 270. | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
By formula: CN- + H2S = (CN- • H2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18.9 ± 1.0 | kcal/mol | TDEq | Meot-ner, 1988 | gas phase; B |
ΔrH° | 19.8 ± 3.5 | kcal/mol | IMRE | Larson and McMahon, 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 23.8 | cal/mol*K | N/A | Larson and McMahon, 1987 | gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 12.9 ± 1.0 | kcal/mol | TDEq | Meot-ner, 1988 | gas phase; B |
ΔrG° | 12.4 ± 2.3 | kcal/mol | IMRE | Larson and McMahon, 1987 | gas phase; B,M |
By formula: C3H7+ + H2S = (C3H7+ • H2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 32.0 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1991 | gas phase; condensation; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 34.8 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1991 | gas phase; condensation; M |
By formula: F- + H2S = (F- • H2S)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 34.6 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1983 | gas phase; These relative affinities are ca. 10 kcal/mol weaker than threshold values (see Wenthold and Squires, 1995) for donors greater than ca. 27 kcal/mol in free energy. This discrepancy has not yet been resolved, though the stronger value appears preferable.; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 18.8 | cal/mol*K | N/A | Larson and McMahon, 1983 | gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 29.0 ± 2.0 | kcal/mol | IMRE | Larson and McMahon, 1983 | gas phase; These relative affinities are ca. 10 kcal/mol weaker than threshold values (see Wenthold and Squires, 1995) for donors greater than ca. 27 kcal/mol in free energy. This discrepancy has not yet been resolved, though the stronger value appears preferable.; B,M |
By formula: F5S- + H2S = (F5S- • H2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 51. ± 12. | kcal/mol | SIFT | Zangerle, Hansel, et al., 1993 | gas phase; CID with Ar; M |
By formula: HS- + H2S = (HS- • H2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 13.2 ± 1.0 | kcal/mol | TDAs | Meot-ner, 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 19.7 | cal/mol*K | PHPMS | Meot-ner, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 7.3 ± 1.0 | kcal/mol | TDAs | Meot-ner, 1988 | gas phase; B |
By formula: H2S+ + H2S = (H2S+ • H2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 21.2 | kcal/mol | PI | Prest, Tzeng, et al., 1983, 2 | gas phase; M |
ΔrH° | 17.0 | kcal/mol | PI | Walters and Blais, 1981 | gas phase; M |
By formula: (H2S+ • H2S) + H2S = (H2S+ • 2H2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.2 | kcal/mol | PI | Prest, Tzeng, et al., 1983, 2 | gas phase; M |
ΔrH° | 3.2 | kcal/mol | PI | Walters and Blais, 1981 | gas phase; M |
By formula: (H2S+ • 2H2S) + H2S = (H2S+ • 3H2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.2 | kcal/mol | PI | Walters and Blais, 1981 | gas phase; M |
By formula: (H2S+ • 3H2S) + H2S = (H2S+ • 4H2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1.4 | kcal/mol | PI | Walters and Blais, 1981 | gas phase; M |
By formula: (H2S+ • 4H2S) + H2S = (H2S+ • 5H2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 2.6 | kcal/mol | PI | Walters and Blais, 1981 | gas phase; M |
By formula: H3S+ + H2S = (H3S+ • H2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15.4 | kcal/mol | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
ΔrH° | 10.8 | kcal/mol | PI | Walters and Blais, 1984 | gas phase; M |
ΔrH° | 10.6 | kcal/mol | PI | Prest, Tzeng, et al., 1983, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 24.4 | cal/mol*K | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
ΔrS° | 17.8 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; Entropy change is questionable; M |
ΔrS° | 18.7 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; M |
By formula: (H3S+ • H2S) + H2S = (H3S+ • 2H2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.1 | kcal/mol | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
ΔrH° | 6.0 | kcal/mol | PI | Walters and Blais, 1984 | gas phase; M |
ΔrH° | 7.2 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20.9 | cal/mol*K | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
ΔrS° | 17.3 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; M |
By formula: (H3S+ • 2H2S) + H2S = (H3S+ • 3H2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 4.4 | kcal/mol | PI | Walters and Blais, 1984 | gas phase; M |
ΔrH° | 8.4 | kcal/mol | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
ΔrH° | 5.4 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 24.5 | cal/mol*K | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
ΔrS° | 14. | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; Entropy change is questionable; M |
By formula: (H3S+ • 3H2S) + H2S = (H3S+ • 4H2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.7 | kcal/mol | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
ΔrH° | 2.5 | kcal/mol | PI | Walters and Blais, 1984 | gas phase; M |
ΔrH° | 3.3 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; Entropy change is questionable; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 24.7 | cal/mol*K | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
ΔrS° | 10. | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Field, 1977 | gas phase; Entropy change is questionable; M |
By formula: (H3S+ • 4H2S) + H2S = (H3S+ • 5H2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.1 | kcal/mol | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 24. | cal/mol*K | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
Free energy of reaction
ΔrG° (kcal/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
1.7 | 185. | PHPMS | Hiraoka and Kebarle, 1977 | gas phase; M |
By formula: H4N+ + H2S = (H4N+ • H2S)
Bond type: Hydrogen bond (positive ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.4 | kcal/mol | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 16.7 | cal/mol*K | PHPMS | Meot-Ner (Mautner) and Sieck, 1985 | gas phase; M |
By formula: I- + H2S = (I- • H2S)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8.8 ± 1.0 | kcal/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
+
= H2NOS-
By formula: NO- + H2S = H2NOS-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 5.60 | kcal/mol | N/A | Hendricks, de Clercq, et al., 2002 | gas phase; B |
Mass spectrum (electron ionization)
Go To: Top, Gas phase ion energetics data, Ion clustering data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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---|---|
NIST MS number | 43 |
Gas Chromatography
Go To: Top, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | PONA | 340. | Yang, Wang, et al., 2004 | 50. m/0.20 mm/0.50 μm, N2, 2. K/min; Tstart: 35. C; Tend: 170. C |
Capillary | PONA | 338. | Yang, Wang, et al., 2003 | 50. m/0.20 mm/0.50 μm, 2. K/min; Tstart: 30. C; Tend: 150. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | PONA | 338. | Yang, Wang, et al., 2003 | 50. m/0.20 mm/0.50 μm; Program: not specified |
Normal alkane RI, polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | TC-Wax | 480. | Ishizaki, Tachihara, et al., 2005 | 60. m/0.25 mm/0.25 μm, N2, 3. K/min, 220. C @ 40. min; Tstart: 70. C |
Normal alkane RI, polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | TC-Wax | 480. | Kraft and Switt, 2005 | Program: not specified |
Capillary | TC-Wax | 480. | Tachihara, Ishizaki, et al., 2004 | Program: not specified |
References
Go To: Top, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Walters and Blais, 1984
Walters, E.A.; Blais, N.C.,
Molecular beam photoionization and fragmentation of D2S, (H2S)2, (D2S)2, and H2S.H2O,
J. Chem. Phys., 1984, 80, 3501. [all data]
Prest, Tzeng, et al., 1983
Prest, H.F.; Tzeng, W.-B.; Brom, J.M., Jr.; Ng, C.Y.,
Molecular beam photoionization study of H2S,
Int. J. Mass Spectrom. Ion Processes, 1983, 50, 315. [all data]
Walters and Blais, 1981
Walters, E.A.; Blais, N.C.,
Molecular beam photoionization of (H2S)n,n = 1 - 7,
J. Chem. Phys., 1981, 75, 4208. [all data]
Smith, Adams, et al., 1981
Smith, D.; Adams, N.G.; Lindinger, W.,
Reactions of the HnS ions (n = 0 to 3) with several molecular gases at thermal energies,
J. Chem. Phys., 1981, 75, 3365. [all data]
Kimura, Katsumata, et al., 1981
Kimura, K.; Katsumata, S.; Achiba, Y.; Yamazaki, T.; Iwata, S.,
Ionization energies, Ab initio assignments, and valence electronic structure for 200 molecules
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Karlsson, Mattsson, et al., 1976
Karlsson, L.; Mattsson, L.; Jadrny, R.; Bergmark, T.; Siegbahn, K.,
Vibrational ans vibronic structure in the valence electron spectrum of H2S,
Phys. Scr., 1976, 13, 229. [all data]
Balkis, Gaines, et al., 1976
Balkis, T.; Gaines, A.F.; Ozgen, G.; Ozgen, I.T.; Flowers, M.C.,
Ionization of hydrogen sul- phide, selenide and telluride by electron impact,
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Rabalais, Debies, et al., 1974
Rabalais, J.W.; Debies, T.P.; Berkosky, J.L.; Huang, J.-T.J.; Ellison, F.O.,
Calculated photoionization cross sections relative experimental photoionization intensities for a selection of small molecules,
J. Chem. Phys., 1974, 61, 516. [all data]
Natalis, 1973
Natalis, P.,
Contribution a la spectroscopie photoelectronique. Effets de l'autoionisation dans less spectres photoelectroniques de molecules diatomiques et triatomiques,
Acad. R. Belg. Mem. Cl. Sci. Collect. 8, 1973, 41, 1. [all data]
Morrison and Traeger, 1973
Morrison, J.D.; Traeger, J.C.,
Ionization and dissociation by electron impact. I. H2O and H2S,
Int. J. Mass Spectrom. Ion Phys., 1973, 11, 77. [all data]
Potts and Price, 1972
Potts, A.W.; Price, W.C.,
Photoelectron spectra and valence shell orbital structures of groups V VI hydrides,
Proc. R. Soc. London A:, 1972, 326, 181. [all data]
Delwiche and Natalis, 1970
Delwiche, J.; Natalis, P.,
Photoelectron spectrometry of hydrogen sulfide,
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Delwiche, Natalis, et al., 1970
Delwiche, J.; Natalis, P.; Collin, J.E.,
High resolution photoelectron spectrometry of H2S and H2Se,
Intern. J. Mass Spectrom. Ion Phys., 1970, 5, 443. [all data]
Dibeler and Liston, 1968
Dibeler, V.H.; Liston, S.K.,
Mass-spectrometric study of photoionization. XI.Hydrogen sulfide and sulfur dioxide,
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Al-Joboury and Turner, 1964
Al-Joboury, M.I.; Turner, D.W.,
Molecular photoelectron spectroscopy. Part II. A summary of ionization potentials,
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Frost and McDowell, 1958
Frost, D.C.; McDowell, C.A.,
Excited states of the molecular ions of hydrogen fluoride, hydrogen iodide, water, hydrogen sulphide, and ammonia,
Can. J. Chem., 1958, 36, 39. [all data]
Watanabe, 1954
Watanabe, K.,
Photoionization and total absorption cross section of gases. I. Ionization potentials of several molecules. Cross sections of NH3 and NO,
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Price, 1935
Price, W.C.,
The far ultraviolet absorption spectra and ionization potentials of H2S, CS2, and SO2,
Bull. Am. Phys. Soc., 1935, 10, 9. [all data]
Bieri, Asbrink, et al., 1982
Bieri, G.; Asbrink, L.; Von Niessen, W.,
30.4-nm He(II) photoelectron spectra of organic molecules,
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Wagner and Bock, 1974
Wagner, G.; Bock, H.,
Photoelektronenspektren und molekuleigenschaften, XXVI. Die delokalisation von schwefel-elektronenpaaren in alkylsulfiden und -disulfiden,
Chem. Ber., 1974, 107, 68. [all data]
Schweig and Thiel, 1974
Schweig, A.; Thiel, W.,
Photoionization cross sections: He I- and He II-photoelectron spectra of homologous oxygen and sulphur compounds,
Mol. Phys., 1974, 27, 265. [all data]
Bock, Wagner, et al., 1972
Bock, H.; Wagner, G.; Kroner, J.,
Photoelektronenspektren und molekuleigenschaften, XIV. Die delokalisation des schwefel-elektronenpaar in CH3S-substituierten aromaten,
Chem. Ber., 1972, 105, 3850. [all data]
Palmer and Lossing, 1962
Palmer, T.F.; Lossing, F.P.,
Free radicals by mass spectrometry. XXVIII. The HS, CH3S, and phenyl-S radicals: ionization potentials and heats of formation,
J. Am. Chem. Soc., 1962, 84, 4661. [all data]
Eland, 1979
Eland, J.H.D.,
Dissociations of state-selected C2H2+, H2S+ and D2S+ ions studied by photoelectron-photoion coincidence spectroscopy,
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Rempala and Ervin, 2000
Rempala, K.; Ervin, K.M.,
Collisional activation of the Endoergic Hydrogen Atom Transfer Reaction S-(2P) + H2 - SH- + H,
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. [all data]
Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr.,
The gas phase acidity scale from methanol to phenol,
J. Am. Chem. Soc., 1979, 101, 6047. [all data]
Shiell, Hu, et al., 1900
Shiell, R.C.; Hu, X.K.; Hu, Q.J.; Hepburn, J.W.,
A determination of the bond dissociation energy (D-0(H-SH)): Threshold ion-pair production spectroscopy (TIPPS) of a triatomic molecule,
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. [all data]
Gurvich, Veyts, et al.
Gurvich, L.V.; Veyts, I.V.; Alcock, C.B.,
Hemisphere Publishing, NY, 1989, V. 1 2, Thermodynamic Properties of Individual Substances, 4th Ed. [all data]
Breyer, Frey, et al., 1981
Breyer, F.; Frey, P.; Hotop, H.,
High Resolution Photoelectron Spectrometry of Negative Ions: Rotational Transitions in Laser-Photodetachment of OH-, SH-, and SD-,
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Notes
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- Symbols used in this document:
AE Appearance energy IE (evaluated) Recommended ionization energy T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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