Tin(II) chloride

• Formula: Cl₂Sn
• Molecular weight: 189.616
• IUPAC Standard InChI: InChI=1S/2ClH.Sn/h2*1H;/q;;+2/p-2 Copy

  
• IUPAC Standard InChIKey: AXZWODMDQAVCJE-UHFFFAOYSA-L Copy
• CAS Registry Number: 7772-99-8
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: SnCl2; Stannous chloride; Tin chloride; Tin chloride (SnCl2); Tin(ii) chloride (1:2); C.I. 77864; NA 1759; NCI-C02722; Stannochlor; Tin dichloride; Tin protochloride; Anhydrous stannous chloride; Fascat 2004; Single muriate of tin; Tin (II) chloride anhydrous; Tin crystals; Tin salt; Tin salts
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Other data available:
  • Vibrational and/or electronic energy levels
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
• Options:
  • Switch to calorie-based units

Gas phase ion energetics data

Go To: Top, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to Cl₂Sn⁺ (ion structure unspecified)

Electron affinity determinations

Ionization energy determinations

Appearance energy determinations

Mass spectrum (electron ionization)

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

For Zoom

1.) Enter the desired X axis range (e.g., 100, 200)

2.) Check here for automatic Y scaling

3.) Press here to zoom

Additional Data

References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pabst, Perry, et al., 1977
Pabst, R.E.; Perry, D.L.; Margrave, J.L.; Franklin, J.L., Electron impact studies of tin tetrahalides SnCl₄, SnBr₄ and SnI₄, Int. J. Mass Spectrom. Ion Phys., 1977, 24, 323. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Novak and Potts, 1984
Novak, I.; Potts, A.W., Ultraviolet photoelectron spectra of gas phase and condensed tin and lead dihalides (MX₂, M = Sn, Pb X = Cl, Br, I), J. Electron Spectrosc. Relat. Phenom., 1984, 33, 1. [all data]

Buchanan, Knowles, et al., 1969
Buchanan, A.S.; Knowles, D.J.; Swingler, D.L., Electron impact studies of stannous chloride and stannic chloride, J. Phys. Chem., 1969, 73, 4394. [all data]

Harris, Lappert, et al., 1976
Harris, D.H.; Lappert, M.F.; Pedley, J.B.; Sharp, G.J., Bonding studies of compounds of group 3-5 elements. Part XVIII. He(I) photoelectron spectra of bivalent homoleptic alkyls and amides, especially of group 4 elements, and of tin(II) chloride and bromide, J. Chem. Soc. Dalton Trans., 1976, 945. [all data]

Evans and Orchard, 1975
Evans, S.; Orchard, A.F., The vapour phase ultra-violet photoelectron spectroscopy of metal halides at elevated temperatures, J. Electron Spectrosc. Relat. Phenom., 1975, 6, 207. [all data]

O'Brien and Mucklejohn, 1987
O'Brien, N.W.; Mucklejohn, S.A., A study of the vapour-phase equilibria over tin(II) chloride, J. Chem. Thermodyn., 1987, 19, 1065. [all data]

Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  AE	Appearance energy
  EA	Electron affinity

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.