iron dichloride


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub48.8 ± 0.96kcal/molN/ABardi, Brunetti, et al., 1996 
Δsub46.1 ± 2.9kcal/molN/ASchoonmaker and Porter, 1958See also Bardi, Brunetti, et al., 1996.

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
47.54 ± 0.48780.TE,MEBardi, Brunetti, et al., 1996Based on data from 693. to 866. K.
45. ± 2.719.TESime and Gregory, 1960Based on data from 694. to 745. K. See also Bardi, Brunetti, et al., 1996.
44.5 ± 2.9640.MSSchoonmaker and Porter, 1958Based on data from 621. to 658. K. See also Bardi, Brunetti, et al., 1996.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
10.0PELee, Potts, et al., 1980LLK
11.5 ± 0.5EISchoonmaker and Porter, 1958RDSH
10.1PEMacNaughton, Bloor, et al., 1981Vertical value; LLK
10.34PELee, Potts, et al., 1980Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
FeCl+12.8 ± 0.5ClEISchoonmaker and Porter, 1958RDSH
Fe+16.5 ± 0.5?EISchoonmaker and Porter, 1958RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bardi, Brunetti, et al., 1996
Bardi, Gianpiero; Brunetti, Bruno; Piacente, Vincenzo, Vapor Pressure and Standard Enthalpies of Sublimation of Iron Difluoride, Iron Dichloride, and Iron Dibromide, J. Chem. Eng. Data, 1996, 41, 1, 14-20, https://doi.org/10.1021/je950115w . [all data]

Schoonmaker and Porter, 1958
Schoonmaker, R.C.; Porter, R.F., Mass spectrometric study of ferrous chloride vapor, J. Chem. Phys., 1958, 29, 116. [all data]

Sime and Gregory, 1960
Sime, R.J.; Gregory, N.W., VAPOR PRESSURES OF FeCl 2 , FeBr 2 AND FeI 2 BY THE TORSION EFFUSION METHOD, J. Phys. Chem., 1960, 64, 1, 86-89, https://doi.org/10.1021/j100830a021 . [all data]

Lee, Potts, et al., 1980
Lee, E.P.F.; Potts, A.W.; Doran, M.; Hillier, I.H.; Delaney, J.J.; Hawksworth, R.W.; Guest, M.F., Photoelectron spectra and electronic structure of the transition metal dichlorides, MCl2(M = Cr, Mn, Fe, Co, Ni), J. Chem. Soc. Faraday Trans. 2, 1980, 76, 506. [all data]

MacNaughton, Bloor, et al., 1981
MacNaughton, R.M.; Bloor, J.E.; Sherrod, R.E.; Schweitzer, G.K., The He(I) photoelectron psectra of some gaseous 3d-transition metal dihalides, J. Electron Spectrosc. Relat. Phenom., 1981, 22, 1. [all data]


Notes

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