iron dichloride
- Formula: Cl2Fe
- Molecular weight: 126.751
- CAS Registry Number: 7758-94-3
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.0 | PE | Lee, Potts, et al., 1980 | LLK |
| 11.5 ± 0.5 | EI | Schoonmaker and Porter, 1958 | RDSH |
| 10.1 | PE | MacNaughton, Bloor, et al., 1981 | Vertical value; LLK |
| 10.34 | PE | Lee, Potts, et al., 1980 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| FeCl+ | 12.8 ± 0.5 | Cl | EI | Schoonmaker and Porter, 1958 | RDSH |
| Fe+ | 16.5 ± 0.5 | ? | EI | Schoonmaker and Porter, 1958 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lee, Potts, et al., 1980
Lee, E.P.F.; Potts, A.W.; Doran, M.; Hillier, I.H.; Delaney, J.J.; Hawksworth, R.W.; Guest, M.F.,
Photoelectron spectra and electronic structure of the transition metal dichlorides, MCl2(M = Cr, Mn, Fe, Co, Ni),
J. Chem. Soc. Faraday Trans. 2, 1980, 76, 506. [all data]
Schoonmaker and Porter, 1958
Schoonmaker, R.C.; Porter, R.F.,
Mass spectrometric study of ferrous chloride vapor,
J. Chem. Phys., 1958, 29, 116. [all data]
MacNaughton, Bloor, et al., 1981
MacNaughton, R.M.; Bloor, J.E.; Sherrod, R.E.; Schweitzer, G.K.,
The He(I) photoelectron psectra of some gaseous 3d-transition metal dihalides,
J. Electron Spectrosc. Relat. Phenom., 1981, 22, 1. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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