cerium trifluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
11.4EIRoberts and Searcy, 1972LLK
28.0 ± 0.7EIZmbov and Margrave, 1968RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Ce+25.2?EIRoberts and Searcy, 1972LLK
FCe+17.2?EIRoberts and Searcy, 1972LLK
CeF+20.5 ± 0.7?EIZmbov and Margrave, 1968RDSH
CeF+13.0 ± 0.7FEIZmbov and Margrave, 1968RDSH
F2Ce+13.5?EIRoberts and Searcy, 1972LLK

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

Fluorine anion + CeF3 = (Fluorine anion • CeF3)

By formula: F- + CeF3 = (F- • CeF3)

Quantity Value Units Method Reference Comment
Δr459. ± 29.kJ/molTherSidorov, Sorokin, et al., 1981gas phase; value altered from reference due to conversion from electron convention to ion convention

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Roberts and Searcy, 1972
Roberts, J.A., Jr.; Searcy, A.W., The stabilities of Ce2F6(g) and La2F6(g), High Temp. Sci., 1972, 4, 411. [all data]

Zmbov and Margrave, 1968
Zmbov, K.F.; Margrave, J.L., Mass spectrometric studies of scandium, yttrium, lanthanum, and rare-earth fluorides, Advan. Chem. Ser., 1968, 72, 267. [all data]

Sidorov, Sorokin, et al., 1981
Sidorov, L.N.; Sorokin, I.D.; Nitikin, N.I.; Skokan, E.V., Effusion method for determining the electron affinity and heat of formation of negative ions, Int. J. Mass Spectrom. Ion Phys., 1981, 39, 311. [all data]


Notes

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