H2S+
- Formula: H2S+
- Molecular weight: 34.080
- CAS Registry Number: 77544-69-5
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: B
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 34710 ± 12 | gas | Potts and Price, 1972 | |||||
Hochlaf, Weitzel, et al., 2004 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | Sym. stretch | 2259 | T | gas | PE | Karlsson, Mattsson, et al., 1976 |
2 | Bend | 800 | T | gas | TPE | Hochlaf, Weitzel, et al., 2004 | |
State: A
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 18518 | gas | A-X | 400 | 500 | Dixon, Duxbury, et al., 1971 | ||
Potts and Price, 1972 | |||||||
Duxbury, Horani, et al., 1972 | |||||||
Karlsson, Mattsson, et al., 1976 | |||||||
Baltzer, Karlsson, et al., 1995 | |||||||
Hochlaf, Weitzel, et al., 2004 | |||||||
Han, Kang, et al., 2010 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | Sym. stretch | 2600 | T | gas | PE | Baltzer, Karlsson, et al., 1995 |
2 | Bend | 950 ± 5 | gas | PE | Potts and Price, 1972 Karlsson, Mattsson, et al., 1976 Baltzer, Karlsson, et al., 1995 | ||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | Sym. stretch | 2496 | gas | PE TPE | Baltzer, Karlsson, et al., 1995 Hochlaf, Weitzel, et al., 2004 | |
2 | Bend | 1159.0 | gas | EF TPE | Duxbury, Horani, et al., 1972 Baltzer, Karlsson, et al., 1995 Hochlaf, Weitzel, et al., 2004 | ||
Additional references: Jacox, 1994, page 24; Jacox, 1998, page 135; Moehlmann and de Heer, 1975
Notes
T | Tentative assignment or approximate value |
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Potts and Price, 1972
Potts, A.W.; Price, W.C.,
Photoelectron spectra and valence shell orbital structures of groups V VI hydrides,
Proc. R. Soc. London A:, 1972, 326, 181. [all data]
Hochlaf, Weitzel, et al., 2004
Hochlaf, M.; Weitzel, K.-M.; Ng, C.Y.,
Vacuum ultraviolet pulsed-field ionization-photoelectron study of H[sub 2]S in the energy range of 10--17 eV,
J. Chem. Phys., 2004, 120, 15, 6944, https://doi.org/10.1063/1.1669386
. [all data]
Karlsson, Mattsson, et al., 1976
Karlsson, L.; Mattsson, L.; Jadrny, R.; Bergmark, T.; Siegbahn, K.,
Vibrational ans vibronic structure in the valence electron spectrum of H2S,
Phys. Scr., 1976, 13, 229. [all data]
Dixon, Duxbury, et al., 1971
Dixon, R.N.; Duxbury, G.; Horani, M.; Rostas, J.,
The H,
Mol. Phys., 1971, 22, 6, 977, https://doi.org/10.1080/00268977100103311
. [all data]
Duxbury, Horani, et al., 1972
Duxbury, G.; Horani, M.; Rostas, J.,
Rotational Analysis of the Electronic Emission Spectrum of the HFormulaSFormula Ion Radical,
Proc. Roy. Soc. (London) A331, 1972, 331, 1584, 109, https://doi.org/10.1098/rspa.1972.0167
. [all data]
Baltzer, Karlsson, et al., 1995
Baltzer, P.; Karlsson, L.; Lundqvist, M.; Wannberg, B.; Holland, D.M.P.; MacDonald, M.A.,
An experimental study of the valence shell photoelectron spectrum of hydrogen sulphide,
Chem. Phys., 1995, 195, 1-3, 403, https://doi.org/10.1016/0301-0104(95)00053-Q
. [all data]
Han, Kang, et al., 2010
Han, S.; Kang, T.Y.; Kim, S.K.,
Rotationally resolved spectroscopy of the A [sup 2]A[sub 1]←X [sup 2]B[sub 1] transition of H[sub 2]S[sup +] above the barrier to linearity using the mass-analyzed threshold ionization photofragment excitation technique,
J. Chem. Phys., 2010, 132, 12, 124304, https://doi.org/10.1063/1.3358252
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Moehlmann and de Heer, 1975
Moehlmann, G.R.; de Heer, F.J.,
Lifetimes of the vibronic Ã2A1 states of H2S+,
Chem. Phys. Lett., 1975, 36, 3, 353, https://doi.org/10.1016/0009-2614(75)80254-5
. [all data]
Notes
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