vanadium trichloride oxide

Formula: Cl₃OV
Molecular weight: 173.300
CAS Registry Number: 7727-18-6
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Gas phase ion energetics data

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Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV)	Method	Reference	Comment
>3.60 ± 0.50	IMRB	Flesch and Svec, 1975	EA: > Cl^-; B

Ionization energy determinations

IE (eV)	Method	Reference	Comment
11.9 ± 0.3	EI	Mason and Behrens, 1982	LBLHLM
11.90 ± 0.05	EI	Flesch and Svec, 1975	LLK
11.6	PE	Burroughs, Evans, et al., 1974	LLK
12.2 ± 0.2	EI	Dillard, 1967	RDSH
11.84	PE	Burroughs, Evans, et al., 1974	Vertical value; LLK

Appearance energy determinations

Ion	AE (eV)	Other Products	Method	Reference	Comment
ClOV⁺	18.1 ± 0.3	2Cl	EI	Mason and Behrens, 1982	LBLHLM
ClOV⁺	16.31 ± 0.05	2Cl	EI	Flesch and Svec, 1975	LLK
ClOV⁺	14.05 ± 0.06	Cl₂	EI	Flesch and Svec, 1975	LLK
ClOV⁺	15.3 ± 0.3	Cl₂	EI	Dillard, 1967	RDSH
ClV⁺	25.0 ± 0.2	2Cl+O	EI	Mason and Behrens, 1982	LBLHLM
ClV⁺	22.16 ± 0.07	2Cl+O	EI	Flesch and Svec, 1975	LLK
ClV⁺	22.6 ± 0.5	2Cl+O	EI	Dillard, 1967	RDSH
Cl₂OV⁺	14.9 ± 0.2	Cl	EI	Mason and Behrens, 1982	LBLHLM
Cl₂OV⁺	13.25 ± 0.05	Cl	EI	Flesch and Svec, 1975	LLK
Cl₂OV⁺	13.7 ± 0.3	Cl	EI	Dillard, 1967	RDSH
Cl₂V⁺	20.8 ± 0.3	Cl+O	EI	Mason and Behrens, 1982	LBLHLM
Cl₂V⁺	18.98 ± 0.20	Cl+O	EI	Flesch and Svec, 1975	LLK
Cl₂V⁺	18.5 ± 0.4	Cl+O	EI	Dillard, 1967	RDSH
Cl₃V⁺	16.48 ± 0.28	O	EI	Flesch and Svec, 1975	LLK
Cl₃V⁺	15.8 ± 0.4	O	EI	Dillard, 1967	RDSH
OV⁺	22.0 ± 0.3	3Cl	EI	Mason and Behrens, 1982	LBLHLM
OV⁺	19.77 ± 0.09	3Cl	EI	Flesch and Svec, 1975	LLK
OV⁺	20.0 ± 0.4	3Cl	EI	Dillard, 1967	RDSH
V⁺	26.83 ± 0.39	3Cl+O	EI	Flesch and Svec, 1975	LLK
V⁺	27.4 ± 0.5	3Cl+O	EI	Dillard, 1967	RDSH

References

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Flesch and Svec, 1975
Flesch, G.D.; Svec, H.J., Thermochemistry of vanadium oxytrichloride and vanadium oxytrifluoride by mass spectrometry, Inorg. Chem., 1975, 14, 1817. [all data]

Mason and Behrens, 1982
Mason, C.F.V.; Behrens, R.G., An electron impact mass spectrometry investigation of VOCl₃(g) and their dissociative fragments, J. Less-Common Met., 1982, 85, 21. [all data]

Burroughs, Evans, et al., 1974
Burroughs, P.; Evans, S.; Hamnett, A.; Orchard, A.F.; Richardson, N.V., He-I photoelectron spectra of some d (0) transition metal compounds, J. Chem. Soc. Faraday Trans. 2, 1974, 70, 1895. [all data]

Dillard, 1967
Dillard, J.G., Gaseous inorganic ion decompositions: a mass spectrometric study of some transition metal compounds, Ph.D. Dissertation, Kansas State University, 1967 (University Microfilms Internal Order 67-9138), 1967. [all data]

Notes

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Symbols used in this document:

AE Appearance energy

EA Electron affinity
Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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