titanium dihydride

• Formula: H₂Ti
• Molecular weight: 49.883
• IUPAC Standard InChI: InChI=1S/Ti.2H Copy

  
• IUPAC Standard InChIKey: COEYXIBLSAIEKV-UHFFFAOYSA-N Copy
• CAS Registry Number: 7704-98-5
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Titanium hydride
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• Information on this page:
  • Condensed phase thermochemistry data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Solid Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Additional references: Jacox, 1994, page 14; Jacox, 1998, page 126

Notes

References

Go To: Top, Condensed phase thermochemistry data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Xiao, Hauge, et al., 1991
Xiao, Z.L.; Hauge, R.H.; Margrave, J.L., Reactions of vanadium and titanium with molecular hydrogen in krypton and argon matrixes at 12 K, J. Phys. Chem., 1991, 95, 7, 2696, https://doi.org/10.1021/j100160a015 . [all data]

Chertihin and Andrews, 1994
Chertihin, G.V.; Andrews, L., Reactions of Laser Ablated Ti Atoms with Hydrogen during Condensation in Excess Argon. Infrared Spectra of the TiH, TiH2, TiH3, and TiH4 Molecules, J. Am. Chem. Soc., 1994, 116, 18, 8322, https://doi.org/10.1021/ja00097a045 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Notes

Go To: Top, Condensed phase thermochemistry data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  S°solid	Entropy of solid at standard conditions
  ΔfH°solid	Enthalpy of formation of solid at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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