Hydrochloric acid-d

• Formula: ClD
• Molecular weight: 37.467
• IUPAC Standard InChI: InChI=1S/ClH/h1H/i/hD Copy

  
• IUPAC Standard InChIKey: VEXZGXHMUGYJMC-DYCDLGHISA-N Copy
• CAS Registry Number: 7698-05-7
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Isotopologues:
  • Hydrogen chloride
• Other names: [2H]hydrogen chloride
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • Constants of diatomic molecules
  • References
  • Notes
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Gas phase thermochemistry data

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Constants of diatomic molecules, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 +  = ( • )

By formula: Cl^- + DCl = (Cl^- • DCl)

Bond type: Hydrogen bond (negative ion to hydride)

Free energy of reaction

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 +  = ( • )

By formula: Cl^- + DCl = (Cl^- • DCl)

Bond type: Hydrogen bond (negative ion to hydride)

Free energy of reaction

Constants of diatomic molecules

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through December, 1976

Notes

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Henderson, Lewis, et al., 1986
Henderson, C.; Lewis, D.G.; Prichard, P.C.; Staveley, L.A.K.; Fonseca, I.M.A.; Lobo, L.Q., Some thermodynamic properties of hydrogen chloride and deuterium chloride, J. Chem. Thermodyn., 1986, 18, 1077. [all data]

Larson and McMahon, 1987
Larson, J.W.; McMahon, T.B., Isotope Effects in Proton Transfer Reactions. An Ion Cyclotron Resonance Determination of the Equilibrium Deuterium Isotope Effect in the Bichloride Ion, J. Phys. Chem., 1987, 91, 3, 554, https://doi.org/10.1021/j100287a013 . [all data]

Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P., The hydrogen bond energies of the bihalide ions XHX- and YHX-, Can. J. Chem., 1985, 63, 1399. [all data]

Weiss, Lawrence, et al., 1970
Weiss, M.J.; Lawrence, G.M.; Young, R.A., Photoelectron spectroscopy of HCI and DCI using molecular beams, J. Chem. Phys., 1970, 52, 2867. [all data]

Terwilliger and Smith, 1973
Terwilliger, D.T.; Smith, A.L., Analysis of autoionizing Rydberg states in the vacuum ultraviolet absorption spectrum of HCl and DCl, J. Mol. Spectrosc., 1973, 45, 366. [all data]

Douglas and Greening, 1979
Douglas; Greening, Unpublished cited in Huber and Herzberg, 1979, 1979, 289. [all data]

Tilford and Ginter, 1971
Tilford, S.G.; Ginter, M.L., Electronic spectra and structure of the hydrogen halides: states associated with the (σ²π³) cπ and (σ²π³) cσ configurations of HCl and DCl, J. Mol. Spectrosc., 1971, 40, 568. [all data]

Stamper, 1962
Stamper, J.G., The vacuum ultraviolet spectrum of DCl, Can. J. Phys., 1962, 40, 1274. [all data]

Pickworth and Thompson, 1953
Pickworth, J.; Thompson, H.W., The fundamental vibration-rotation band of deuterium chloride, Proc. R. Soc. London A, 1953, 218, 37. [all data]

Van Horne and Hause, 1956
Van Horne, B.H.; Hause, C.D., Near infrared spectrum of DCl, J. Chem. Phys., 1956, 25, 56. [all data]

Mould, Price, et al., 1960
Mould, H.M.; Price, W.C.; Wilkinson, G.R., Infra-red emission from gases excited by a radio-frequency discharge, Spectrochim. Acta, 1960, 16, 479. [all data]

Hansler and Oetjen, 1953
Hansler, R.L.; Oetjen, R.A., The infrared spectra of HCl, DCl, HBr, and NH₃ in the region from 40 to 140 microns, J. Chem. Phys., 1953, 21, 1340. [all data]

Cowan and Gordy, 1958
Cowan, M.; Gordy, W., Precision measurements of millimeter and submillimeter wave spectra: DCl, DBr, and DI, Phys. Rev., 1958, 111, 209. [all data]

De Lucia, Helminger, et al., 1971
De Lucia, F.C.; Helminger, P.; Gordy, W., Submillimeter-wave spectra and equilibrium structures of the hydrogen halides, Phys. Rev. A: Gen. Phys., 1971, 3, 1849. [all data]

Rosenberg, Lightman, et al., 1972
Rosenberg, A.; Lightman, A.; Ben-Reuven, A., Interferometric measurements of the pure rotational spectra of HCl and DCl, J. Quant. Spectrosc. Radiat. Transfer, 1972, 12, 219. [all data]

Kaiser, 1970
Kaiser, E.W., Dipole moment and hyperfine parameters of H³⁵Cl and D³⁵Cl, J. Chem. Phys., 1970, 53, 1686. [all data]

Rank, Eastman, et al., 1962
Rank, D.H.; Eastman, D.P.; Rao, B.S.; Wiggins, T.A., Rotational and vibrational constants of the HCl³⁵ and DCl³⁵ molecules, J. Opt. Soc. Am., 1962, 52, 1. [all data]

Webb and Rao, 1968
Webb, D.U.; Rao, K.N., Vibration rotation bands of heated hydrogen halides, J. Mol. Spectrosc., 1968, 28, 121. [all data]

Crane-Robinson and Thompson, 1963
Crane-Robinson, C.; Thompson, H.W., Pressure broadening studies on vibration-rotation bands. IV. Optical collision diameters for foreign-gas broadening of CO and DCl bands, Proc. R. Soc. London A, 1963, 272, 453. [all data]

James and Thibault, 1964
James, T.C.; Thibault, R.J., Pressure broadening of DCl by HCl and of HCl by DCl. A comparison of experimental results with Anderson's theory, J. Chem. Phys., 1964, 40, 534. [all data]

Jaffe, Hirshfeld, et al., 1964
Jaffe, J.H.; Hirshfeld, M.A.; Ben-Reuven, A., Pressure-induced shifts of DCl lines due to HCl: shift oscillation, J. Chem. Phys., 1964, 40, 1705. [all data]

Smith, 1973
Smith, F.G., Dipole moment function and vibration-rotation matrix elements of HCl³⁵ and DCl³⁵, J. Quant. Spectrosc. Radiat. Transfer, 1973, 13, 717. [all data]

Kaiser, 1974
Kaiser, E.W., Note: Comment to "Dipole moment function and vibration-rotation matrix elements of HCl³⁵ and DCl³⁵", J. Quant. Spectrosc. Radiat. Transfer, 1974, 14, 317. [all data]

Tokuhiro, 1967
Tokuhiro, T., Vibrational and rotational effects on the nuclear quadrupole coupling constants in hydrogen, deuterium, and tritium halides, J. Chem. Phys., 1967, 47, 109. [all data]

Corneil and Pimentel, 1968
Corneil, P.H.; Pimentel, G.C., Hydrogen-chlorine explosion laser. II. DCl, J. Chem. Phys., 1968, 49, 1379. [all data]

Davies and Hallam, 1971
Davies, J.B.; Hallam, H.E., Infra-red cryogenic studies. Part 6. Deuterium chloride in argon and other matrices, Trans. Faraday Soc., 1971, 677, 3176. [all data]

Benedict, Herman, et al., 1956
Benedict, W.S.; Herman, R.; Moore, G.E.; Silverman, S., The strengths, widths, and shapes of infrared lines. II. The HCl fundamental, Can. J. Phys., 1956, 34, 850. [all data]

Huber and Herzberg, 1979
Huber, K.P.; Herzberg, G., Molecular Spectra and Molecular Structure. IV. Constants of Diatomic Molecules, Van Nostrand Reinhold Company, New York, 1979, 716. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Constants of diatomic molecules, References

• Symbols used in this document:
  

  Pc	Critical pressure
  Ptriple	Triple point pressure
  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  T	Temperature
  Tc	Critical temperature
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔrG°	Free energy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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