sodium fluoride
- Formula: FNa
- Molecular weight: 41.9881725
- IUPAC Standard InChI: InChI=1S/FH.Na/h1H;/q;+1/p-1
- IUPAC Standard InChIKey: PUZPDOWCWNUUKD-UHFFFAOYSA-M
- CAS Registry Number: 7681-49-4
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 0.520 ± 0.010 | LPES | Miller, Leopold, et al., 1986 | B |
| 1.10 ± 0.20 | LPES | Miller and Lineberger, 1990 | Vertical Detachment Energy: 1.5±0.1 eV; B |
| 0.41998 | NBAE | De Vreugd, Wijnaendts van Resandt, et al., 1979 | B |
| 1.12 ± 0.21 | EIAE | Shevchenko, Iljin, et al., 1976 | From Na2BO2F; B |
| >1.34997 | EIAE | Ebinghaus, 1964 | From (NaF)2; B |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| Na+ | 9.98 ± 0.15 | F | EI | Shevchenko, Iljin, et al., 1976 | LLK |
| Na+ | 9.9 ± 0.2 | F | EI | Hastie, Zmbov, et al., 1968 | RDSH |
| Na+ | ~12. | F | EI | Porter and Schoonmaker, 1958 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C.,
Electron Affinities of the Alkali Halides and the Structure of their Negative Ions,
J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091
. [all data]
Miller and Lineberger, 1990
Miller, T.M.; Lineberger, W.C.,
Mass Spectra and Photodetachment of Sodium Fluoride Negative Ion Clusters,
Int. J. Mass Spectrom. Ion Proc., 1990, 102, 239, https://doi.org/10.1016/0168-1176(90)80063-9
. [all data]
De Vreugd, Wijnaendts van Resandt, et al., 1979
De Vreugd, C.; Wijnaendts van Resandt, R.W.; Los, J.; Smith, B.,
Differential Cross Sections for Collisions of Negative Halogen Ions and Alkali Atoms,
Chem. Phys., 1979, 42, 3, 305, https://doi.org/10.1016/0301-0104(79)80078-6
. [all data]
Shevchenko, Iljin, et al., 1976
Shevchenko, V.E.; Iljin, M.K.; Nikitin, O.T.; Sidorov, L.N.,
Mass-spectrometric study of mixed dimers M2BO2F,
Int. J. Mass Spectrom. Ion Phys., 1976, 21, 279. [all data]
Ebinghaus, 1964
Ebinghaus, H.Z.,
Negative Ionen aus Alkalihalogeniden und Electronenaffinitaten der Alkalimetalle und Alkalihalogenide,
Z. Naturfor., 1964, 19A, 727. [all data]
Hastie, Zmbov, et al., 1968
Hastie, J.W.; Zmbov, K.F.; Margrave, J.L.,
Mass spectrometric studies at high temperatures. XXIII. Vapor equilibria over molten NaSnF3 and KSnF3,
J. Inorg. Nucl. Chem., 1968, 30, 729. [all data]
Porter and Schoonmaker, 1958
Porter, R.F.; Schoonmaker, R.C.,
Mass spectrometric study of the vaporization of LiF, NaF, and LiF-NaF mixtures,
J. Chem. Phys., 1958, 29, 1070. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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