N-Methyldiethanolamine, 2TMS derivative
- Formula: C11H29NO2Si2
- Molecular weight: 263.5245
- IUPAC Standard InChI: InChI=1S/C11H29NO2Si2/c1-12(8-10-13-15(2,3)4)9-11-14-16(5,6)7/h8-11H2,1-7H3
- IUPAC Standard InChIKey: FAJPYHFAPOGNPE-UHFFFAOYSA-N
- CAS Registry Number: 76710-52-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Methanamine, N,N-di(2-trimethylsilyloxyethyl)-; Methanamine, N,N-bis-[2-(trimethylsiloxy)ethyl]-; Methyl bis-[2-(trimethylsilyloxy)ethyl] amine
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.34 | PE | Brodskaya, Voronkov, et al., 1987 | Vertical value |
Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | SE-54 | 1314. | Kostiainen, 2000 | 25. m/0.32 mm/0.25 μm, He, 40. C @ 1. min, 10. K/min, 280. C @ 10. min |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | 5 % Phenyl methyl siloxane | 1314. | OPCW, 1997 | Program: not specified |
References
Go To: Top, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Brodskaya, Voronkov, et al., 1987
Brodskaya, E.I.; Voronkov, M.G.; Toryashinova, D.D.; Baryshok, V.P.; Ratovski, G.V.; Chuvashev, D.D.; Efremov, V.G.,
Intramolecular interactions in compounds bearing Si-O-C-C-N or C-O-C-C-N fragments,
J. Organomet. Chem., 1987, 336, 49. [all data]
Kostiainen, 2000
Kostiainen, O.,
Gas Chromatography in Screening of Chemicals Related to the Chemical Weapons Convention
in Encyclopedia of Analytical Chemistry, Meyers, R.A., ed(s)., John Wiley Sons Ltd, Chichester, 2000, 963-979. [all data]
OPCW, 1997
OPCW,
Conference of the States Parties C-I/DEC.64 (22 May 1997), 1997, retrieved from http://www.opcw.org/html/global/cseries/csp1/CIDEC64.html. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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