1-Tetradecyne

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Phase change data

Go To: Top, Gas phase ion energetics data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert L. Brown and Stephen E. Stein

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference
405. to 407.0.018Farchan Laboratories, 1990

Gas phase ion energetics data

Go To: Top, Phase change data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
9.89 ± 0.02PIRang and Martinson, 1978LLK

Gas Chromatography

Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-101110.1413.Kuningas, Rang, et al., 1990He; Column length: 50. m; Column diameter: 0.25 mm
CapillaryApiezon L150.1396.Rang, Kuningas, et al., 1976N2; Column length: 50. m; Column diameter: 0.25 mm
CapillaryApiezon L170.1397.Rang, Kuningas, et al., 1976N2; Column length: 50. m; Column diameter: 0.25 mm
CapillaryApiezon L190.1398.Rang, Kuningas, et al., 1976N2; Column length: 50. m; Column diameter: 0.25 mm

Kovats' RI, polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryPEG-20M80.1603.5Orav, Kuningas, et al., 1993100. m/0.25 mm/0.12 μm
CapillaryPEG-20M80.1626.2Orav, Kuningas, et al., 1993100. m/0.25 mm/0.24 μm
CapillaryPEG-20M80.1627.4Orav, Kuningas, et al., 199360. m/0.32 mm/0.25 μm
CapillaryPEG 4000110.1633.Rang, Orav, et al., 1988 
CapillaryPEG 4000120.1633.Rang, Orav, et al., 1988 
CapillaryPEG 4000140.1633.Rang, Orav, et al., 1988 
CapillaryPEG 4000150.1632.Rang, Orav, et al., 1988 
CapillaryPEG 4000160.1633.Rang, Orav, et al., 1988 
CapillaryPEG-20M80.1603.5Orav, Kuningas, et al., 1985Column length: 100. m; Column diameter: 0.25 mm
CapillaryPEG-20M80.1626.2Orav, Kuningas, et al., 1985Column length: 100. m; Column diameter: 0.25 mm

References

Go To: Top, Phase change data, Gas phase ion energetics data, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Farchan Laboratories, 1990
Farchan Laboratories, Research Chemicals Catalog, Farchan Laboratories, Gainesville, FL, 1990, 91. [all data]

Rang and Martinson, 1978
Rang, S.; Martinson, E., Ionization potentials of unsaturated hydrocarbons. 3. n-Alkyunes C8-C12., Eesti. NSV Tead. Akad. Toim. Keem., 1978, 44. [all data]

Kuningas, Rang, et al., 1990
Kuningas, K.; Rang, S.; Kailas, T., Relationship between the structure and retention of n-alkenes and n-alkynes on silicone phases, J. Chromatogr., 1990, 520, 137-148, https://doi.org/10.1016/0021-9673(90)85094-C . [all data]

Rang, Kuningas, et al., 1976
Rang, S.; Kuningas, K.; Orav, A.; Eisen, O., Capillary gas chromatography of n-alkynes. I. Retention indices, J. Chromatogr., 1976, 119, 451-460, https://doi.org/10.1016/S0021-9673(00)86807-7 . [all data]

Orav, Kuningas, et al., 1993
Orav, A.; Kuningas, K.; Rang, S., A comparison of different retention index systems with unsaturated and aromatic hydrocarbons in capillary gas chromatography on PEG 20MK, Chromatographia, 1993, 37, 7/8, 411-414, https://doi.org/10.1007/BF02272257 . [all data]

Rang, Orav, et al., 1988
Rang, S.A.; Orav, A.E.; Kuningas, K.R.; Meister, A.E.; Strense, T.V.; Eisen, O.G., Gas-Chromatographic Characteristics of unsaturated hydrocarbons, Academy of Sciences of Estonia SSR, Tallinn, Estonia SSR, 1988, 208. [all data]

Orav, Kuningas, et al., 1985
Orav, A.; Kuningas, K.; Rang, S.; Eisen, O., Capillary gas chromatography of n-tridecenes, n-tetradecenes and C10-C14 n-alkynes on polyethylene glycol 20m of different polarity, Eesti NSV Tead. Akad. Toim. Keem., 1985, 34, 2, 105-113. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Gas Chromatography, References