Antimony pentachloride
- Formula: Cl5Sb
- Molecular weight: 299.025
- IUPAC Standard InChI: InChI=1S/5ClH.Sb/h5*1H;/q;;;;;+5/p-5
- IUPAC Standard InChIKey: VMPVEPPRYRXYNP-UHFFFAOYSA-I
- CAS Registry Number: 7647-18-9
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: SbCl5; Antimony(V) chloride; Antimony chloride; Antimony chloride (SbCl5); Antimonpentachlorid; Antimoonpentachloride; Antimony perchloride; Pentachloroantimony; Pentachlorure d'antimoine; Perchlorure d'antimoine; UN 1730; Antimony pentachloride (SbCl5)
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Options:
Phase change data
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, NIST Free Links, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
| Temperature (K) | A | B | C | Reference | Comment |
|---|---|---|---|---|---|
| 295.9 - 387.3 | 4.89114 | 2046.733 | -32.292 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
Gas phase ion energetics data
Go To: Top, Phase change data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, NIST Free Links, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.8 | PE | Elbel and tom Dieck, 1981 | LLK |
| 11.47 ± 0.15 | PE | Elbel and tom Dieck, 1981 | Vertical value; LLK |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, Gas phase ion energetics data, Vibrational and/or electronic energy levels, NIST Free Links, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.
Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
| Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | Chemical Concepts |
| NIST MS number | 156183 |
Vibrational and/or electronic energy levels
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), NIST Free Links, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Takehiko Shimanouchi
Symmetry: D3h Symmetry Number σ = 6
| Sym. | No | Approximate | Selected Freq. | Infrared | Raman | Comments | ||||
|---|---|---|---|---|---|---|---|---|---|---|
| Species | type of mode | Value | Rating | Value | Phase | Value | Phase | |||
| a1' | 1 | SbCl3 s-str | 357 | C | 357 p | liq. | ||||
| a1' | 2 | SbCl2 s-str | 307 | C | 306 W | liq. | 307 dp | liq. | ||
| a2 | 3 | SbCl2 a-str | 384 | C | 384 VS | gas | ||||
| a2 | 4 | SbCl3 op-deform | 154 | D | 154 | solid solid | ||||
| e' | 5 | SbCl3 d-str | 398 | C | 398 VS | gas | 397 | liq. | ||
| e' | 6 | SbCl3 d-deform | 177 | C | 172 S | solid solid | 177 dp | liq. | ||
| e' | 7 | SbCl bend | 72 | D | 72 dp | liq. | ||||
| e | 8 | SbCl bend | 165 | C | 165 dp | liq. | ||||
Source: Shimanouchi, 1972
Notes
| VS | Very strong |
| S | Strong |
| W | Weak |
| p | Polarized |
| dp | Depolarized |
| C | 3~6 cm-1 uncertainty |
| D | 6~15 cm-1 uncertainty |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, NIST Free Links, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Elbel and tom Dieck, 1981
Elbel, S.; tom Dieck, H.,
Die stiborane Me3SbX2 (X = Me, Cl, Br, I) und SbCl5 - im vergleich mit nebengruppenanaloga TaMe5, TaCl5 und NbCl5,
Z. Anorg. Allg. Chem., 1981, 483, 33. [all data]
Shimanouchi, 1972
Shimanouchi, T.,
Tables of Molecular Vibrational Frequencies Consolidated Volume II,
J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, NIST Free Links, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.