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Antimony pentachloride


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
295.9 - 387.34.891142046.733-32.292Stull, 1947Coefficents calculated by NIST from author's data.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - S.G. Lias, R.D. Levin, and S.A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
10.8PEElbel and tom Dieck, 1981LLK
11.47 ± 0.15PEElbel and tom Dieck, 1981Vertical value; LLK

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spec Data Center, S.E. Stein, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 156183

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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: T. Shimanouchi

Symmetry:   D3h     Symmetry Number sigma = 6


 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase

a1' 1 SbCl3 s-str 357  C 357 p liq.
a1' 2 SbCl2 s-str 307  C 306 W liq. 307 dp liq.
a2 3 SbCl2 a-str 384  C 384 VS gas
a2 4 SbCl3 op-deform 154  D 154 solid solid
e' 5 SbCl3 d-str 398  C 398 VS gas 397 liq.
e' 6 SbCl3 d-deform 177  C 172 S solid solid 177 dp liq.
e' 7 SbCl bend 72  D 72 dp liq.
e 8 SbCl bend 165  C 165 dp liq.

Source: Shimanouchi, 1972

Notes

VSVery strong
SStrong
WWeak
pPolarized
dpDepolarized
C3~6 cm-1 uncertainty
D6~15 cm-1 uncertainty

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Elbel and tom Dieck, 1981
Elbel, S.; tom Dieck, H., Die stiborane Me3SbX2 (X = Me, Cl, Br, I) und SbCl5 - im vergleich mit nebengruppenanaloga TaMe5, TaCl5 und NbCl5, Z. Anorg. Allg. Chem., 1981, 483, 33. [all data]

Shimanouchi, 1972
Shimanouchi, T., Tables of Molecular Vibrational Frequencies Consolidated Volume II, J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]


Notes

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