caesium chloride
- Formula: ClCs
- Molecular weight: 168.358
- IUPAC Standard InChIKey: AIYUHDOJVYHVIT-UHFFFAOYSA-M
- CAS Registry Number: 7647-17-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Cesium chloride
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Condensed phase thermochemistry data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -103.84 | kcal/mol | Review | Chase, 1998 | Data last reviewed in June, 1968 |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid,1 bar | 24.309 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1968 |
Quantity | Value | Units | Method | Reference | Comment |
ΔfH°solid | -105.84 | kcal/mol | Review | Chase, 1998 | Data last reviewed in June, 1968 |
Quantity | Value | Units | Method | Reference | Comment |
S°solid | 24.183 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in June, 1968 |
Liquid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 918. to 3000. |
---|---|
A | 18.50000 |
B | -6.350581×10-11 |
C | 3.544941×10-11 |
D | -6.139090×10-12 |
E | -1.857461×10-12 |
F | -109.3560 |
G | 46.69689 |
H | -103.8400 |
Reference | Chase, 1998 |
Comment | Data last reviewed in June, 1968 |
Solid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 743. | 743. to 918. |
---|---|---|
A | 10.61950 | 14.54640 |
B | 6.652500 | 0.730741 |
C | -1.972620 | 0.271368 |
D | 0.948517 | -0.051622 |
E | 0.007110 | -0.037685 |
F | -109.2630 | -109.9370 |
G | 35.17051 | 41.42510 |
H | -105.8400 | -105.8400 |
Reference | Chase, 1998 | Chase, 1998 |
Comment | Data last reviewed in June, 1968 | Data last reviewed in June, 1968 |
Gas phase ion energetics data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
0.46 ± 0.10 | LPES | Miller, Leopold, et al., 1986 | B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.4 | PE | Benson, Novak, et al., 1987 | LBLHLM |
8.8 | EI | Williams, 1982 | LBLHLM |
8.3 ± 0.1 | PE | Potts and Price, 1977 | LLK |
8.3 ± 0.1 | PE | Potts, Williams, et al., 1974 | LLK |
7.84 ± 0.05 | PE | Berkowitz, Dehmer, et al., 1973 | LLK |
8.3 ± 0.3 | EI | Bloom, Hastie, et al., 1968 | RDSH |
8.7 ± 0.1 | PE | Timoshenko and Akopyan, 1974 | Vertical value; LLK |
8.5 | PE | Goodman, Allen, et al., 1974 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
Cs+ | 8.47 ± 0.07 | Cl | PI | Berkowitz, 1969 | RDSH |
Cs+ | 17.46 ± 0.04 | Cl(-) | PE | Potts and Price, 1977 | Vertical value; LLK |
Cs+ | 18.86 ± 0.04 | Cl(-) | PE | Potts and Price, 1977 | Vertical value; LLK |
References
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Miller, Leopold, et al., 1986
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C.,
Electron Affinities of the Alkali Halides and the Structure of their Negative Ions,
J. Chem. Phys., 1986, 85, 5, 2368, https://doi.org/10.1063/1.451091
. [all data]
Benson, Novak, et al., 1987
Benson, J.M.; Novak, I.; Potts, A.W.,
Photoelectron spectroscopy of the caesium halides using synchrotron radiation,
J. Phys. B:, 1987, 20, 6257. [all data]
Williams, 1982
Williams, D.J.,
Mass spectrometric study of the vaporization of the alkali chloride-cuprous chloride systems,
Aust. J. Chem., 1982, 35, 1531. [all data]
Potts and Price, 1977
Potts, A.W.; Price, W.C.,
Photoelectron studies of ionic materials using molecular beam techniques,
Phys. Scr., 1977, 16, 191. [all data]
Potts, Williams, et al., 1974
Potts, A.W.; Williams, T.A.; Price, W.C.,
Photoelectron spectra and electronic structure of diatomic alkali halides,
Proc. Roy. Soc. London A, 1974, 341, 147. [all data]
Berkowitz, Dehmer, et al., 1973
Berkowitz, J.; Dehmer, J.L.; Walker, T.E.H.,
PES of high-temperature vapors. IV. The cesium halides. Effect of spin-orbit interaction on the photoelectron and mass spectra of the alkali halides,
J. Chem. Phys., 1973, 59, 3645. [all data]
Bloom, Hastie, et al., 1968
Bloom, H.; Hastie, J.W.; Morrison, J.D.,
Ionization and dissociation of the alkali halides by electron impact,
J. Phys. Chem., 1968, 72, 3041. [all data]
Timoshenko and Akopyan, 1974
Timoshenko, M.M.; Akopyan, M.E.,
Photoelectron spectra of cesium halides,
High Energy Chem., 1974, 8, 175, In original 211. [all data]
Goodman, Allen, et al., 1974
Goodman, T.D.; Allen, J.D., Jr.; Cusachs, L.C.; Schweitzer, G.K.,
The photoelectron spectra of gaseous alkali halides,
J. Electron Spectrosc. Relat. Phenom., 1974, 3, 289. [all data]
Berkowitz, 1969
Berkowitz, J.,
Photoionization of high-temperature vapors. V. Cesium halides; chemical shift of autoionization,
J. Chem. Phys., 1969, 50, 3503. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy EA Electron affinity S°liquid,1 bar Entropy of liquid at standard conditions (1 bar) S°solid Entropy of solid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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